Substituted barium titanate and barium strontium titanate...

Compositions: ceramic – Ceramic compositions – Titanate – zirconate – stannate – niobate – or tantalate or...

Reexamination Certificate

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C501S139000, C333S161000, C250S250000

Reexamination Certificate

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06916755

ABSTRACT:
This invention provides the three novel La,Fe, La,Cr and Sm,Fe substituted barium titanate solid solution ferroelectric compositions with the formula Ba1-xLnxTi1-xMxO3wherein when Ln is La, M is Fe or Cr, when Ln is Sm, M is Fe and x is from about 0.02 to about 0.06 and mixtures thereof, the novel La,Fe substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLaxTi1-xFexO3wherein y is greater than zero and less than about 0.6 and x is from about 0.01 to about 0.06 and the novel La,Al substituted barium strontium titanate solid solution ferroelectric compositions with the formula (Ba1-ySry)1-xLaxTi1-x/4 3a/4Ala(x-a)/4O3wherein denotes a vacancy, y is greater than zero and less than about 0.6, a is from about 0.01 to about 0.06 and x is from 0.02 to about 0.10 with the proviso that x is greater than or equal to a. These low loss tunable ferroelectric compositions are especially useful in tunable microwave thin film devices which fall into three types: interdigital and trilayer capacitors, coplanar waveguides and microstrips.

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S. Skapin et al; Chemical Reactions and Dielectric Properties of the BaTiO3—LaAIO3and BaTiO3—LaAIO3—LaTI3/4O3Systems;Journal of Solid State Chemistry129, pp. 223-230 (1997); Academic Press.
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