Substituted 5-aryl-2-(2-hydroxyphenyl)-2H-benzotriazole UV...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...

Reexamination Certificate

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C524S099000, C524S100000, C524S102000, C524S186000, C524S205000, C524S287000, C524S291000, C524S359000, C524S399000, C524S430000, C044S275000, C431S288000, C252S403000

Reexamination Certificate

active

10812728

ABSTRACT:
Compounds of formula I or IIwhere R is an aryl moiety, such as phenyl, naphthyl or biphenylyl, or is phenyl substituted by one or more trifluoromethyl, bromo or cyano, and E1and E2are independently hydrogen, alkyl, aralkyl and the like are prepared by reaction of a benzotriazole substituted on the 5-position of the benzo ring by a halogen atom with a arylboronic acid or ester in the presence of a transition-metal catalyst, such as palladium (II) diacetate. The benzotriazole compounds of formula I are particularly efficacious as stabilizers for automotive coatings and candle wax.

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J. L. Gerlock et al., Proc. 36thAnnual Tech. Sym., May 18, 1993.

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