Substituted 1-oxyalkyl-2,6,6-trimethyl-cyclohexene derivatives,

Details Substituted 1-oxyalkyl-2,6,6-trimethyl-cyclohexene derivatives, Substituted 1-oxyalkyl-2,6,6-trimethyl-cyclohexene derivatives,

Filed on

1979-01-16

Date issued

1980-05-13

Examiner

Morgenstern, Norman

Patent Class

Organic compounds -- part of the class 532-570 series

SubClass

Organic compounds

SubSubClass

Oxygen containing

Other Related Categories

568378, C07F 302

Type

Patent

Status

active

Patent number

042029945

Description

ABSTRACT:
Described are substituted 1-oxyalkyl-2,6,6-trimethylcyclohexene derivatives having the generic structure: ##STR1## wherein R.sub.1 is one of OH, ##STR2## OMgX or H; R.sub.2 is ##STR3## OH, OMgX, CH.sub.3, H; R.sub.3 is one of methyl, ethyl, 1-propyl or 2-propyl; X is chloro, bromo or iodo; R.sub.6 is hydrogen or no moiety; one of the wavy lines is a carbon-carbon double and the other of the wavy lines is a carbon-carbon single bond; with the first proviso that when the .DELTA..sup.2,3 bond is a carbon-carbon double bond, then R.sub.6 is hydrogen and the moieties R.sub.6 and ##STR4## are so juxtaposed as to give rise to two different groups of stereoisomers of the molecular genus: ##STR5## and with the second proviso that when R.sub.1 is one of ##STR6## OH or OMgX then R.sub.2 is hydrogen or methyl; and when R.sub.2 is one of ##STR7## OH or OMgX then R.sub.1 is hydrogen. Also described are processes for preparing such 1-oxyalkyl-2,6,6-trimethyl cyclohexene derivatives and organoleptic uses of such 1-oxyalkyl-2,6,6-trimethyl cyclohexene derivatives, with the exception of compounds wherein one of R.sub.1 or R.sub.2 is OMgX.

REFERENCES:
patent: 3899597 (1975-08-01), Mookherjee et al.
patent: 3928248 (1975-12-01), Mookherjee et al.
patent: 3931326 (1976-01-01), Kovats et al.
patent: 3932485 (1976-01-01), Surmatis
patent: 4054606 (1977-10-01), Naf

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