Substituted 1,2-dihydropyridines and process for preparing same

Details Substituted 1,2-dihydropyridines and process for preparing same Substituted 1,2-dihydropyridines and process for preparing same

1974-04-17

1977-03-22

Gallagher, R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260290S, 260290HL, 2602949, 260295R, 260283SC, C07D21558, C07D21192

Patent

active

040136612

ABSTRACT:
Substituted 1,2-dihydropyridines of the formula ##SPC1##
In which R and R.sup.2 are selected from the group consisting of hydrogen, --NH.sub.2, silyl, silyl linked via oxygen, silyl linked via nitrogen, sulfamyl, organosulfonamido, nitro, organic radical, organic radical linked via oxygen, organic radical linked via sulfur, organic radical linked via nitrogen, organic radical linked via --SO-- and organic radical linked via --SO.sub.2 --; with the proviso that the R.sup.2 groupings when joined together form an ortho condensed cyclic or polycyclic hydrocarbon; R.sup.1 is a member selected from the group consisting of hydrogen, --NH.sub.2, silyl, silyl linked via oxygen, silyl linked via nitrogen, sulfamyl, organosulfonamido, nitro, organic radical, organic radical linked via oxygen, organic radical linked via sulfur, organic radical linked via nitrogen, organic radical linked via --SO-- organic radical linked via --SO.sub.2 --, mercapto, sulfino and sulfo; R.sup.3 is a member selected from the group consisting of hydrogen, halogen, and methyl; and Z is a member selected from the group consisting of halogen and an electron-withdrawing group containing an electronegative atom doubly or triply bonded to a more positive atom which atom is singly bonded to the carbon atom attached to the pyridine ring. Exemplary of such compositions is 1,4-bis(trimethylsilyl)-2-(1-cyanoethyl)-1,2-dihydropyridine. The compounds of the invention are useful as antioxidants for polyphenyl ethers, as stabilizers for halogenated polyhydrocarbons, as curing agents for silicones and epoxide resins, as dyeing improvers for polyesters and as fuel additives for imparting hypergolic properties.

REFERENCES:
patent: 3816439 (1974-06-01), Sulzbach et al.
Shostrakovskii et al., Chem. Abstr., vol. 59, 11550e-11550h, Nov. 1963.

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