Substantially spherical supramolecular assemblies

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S720000

Reexamination Certificate

active

10408605

ABSTRACT:
Disclosed are the general principles upon which closed molecular or ionic structural frameworks may be prepared. These frameworks are based upon the self-assembly (wherein the term self-assembly refers to the association of chemical components through inter-component bonds) of n>4 subunits where surface curvature is supplied by edge sharing of subunits.

REFERENCES:
Leonard R. MacGillivray and Jerry L. Atwood□□A Chiral sperical molecular assembly held together by 60 hydrogen bonds□□□□Nature 389, 469-472 (Oct. 2, 1997).□□
Peter Timmerman, Willem Verboom, Frank C.J.M. van Veggel, John P.M. van Duynhoven and David N. Reinhoudt□□A Novel Type of Stereoisomerism in Calix[4]arene-Based Carceplexes□□□□Angew. Chem. Int. Ed. Engl. 1994,33,No. 22 pp. 2345-2348.
Peter Timmerman, Willem Verboom, Frank C.J.M. van Veggel, Willem P. van Hoorn, and David N. Reinhoudt□□An Organic Molecule with a Rigid Cavity of Nanosize Dimensions□□□□Angew. Chem. Int. Ed. Engl. 1994,33,No. 12 pp. 1292-1294.

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