Stretchable laminate

Fabric (woven – knitted – or nonwoven textile or cloth – etc.) – Coated or impregnated woven – knit – or nonwoven fabric which... – Coating or impregnation improves elasticity – bendability,...

Reexamination Certificate

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Details

C442S104000, C442S394000, C442S408000, C428S904000

Reexamination Certificate

active

06750161

ABSTRACT:

TECHNICAL FIELD
The present invention relates generally to substrates having elastomeric coatings thereon, such as synthetic leather, and more particularly to a stretchable laminate comprising a hydroentangled nonwoven fabric substrate exhibiting extensibility and recovery in the cross-direction, and an elastomeric coating applied thereto.
BACKGROUND OF THE INVENTION
Nonwoven fabrics are used in a very wide variety of applications where the engineered qualities of the fabric can be advantageously employed. These types of fabrics differ from traditional woven or knitted fabrics in that the fibers or filaments of the fabric are integrated into a coherent web without traditional textile processes. Entanglement of the fibers or filaments of the fabric provide the fabric with the desired integrity, with the application of binder compositions and the like being well known for further enhancing the integrity of the structure.
Various parameters impact the physical characteristics of the nonwoven fabric, including fiber composition and size, fiber orientation, fiber entanglement, and integration of the fibers such as by application of binders or thermal bonding. Variations in these parameters permit fabrics to be engineered for specific applications, thus enhancing the cost-effectiveness of such materials.
While fabrics of this nature have found widespread applicability, the nature of the processes by which they are typically formed can limit the uses for which particular fabrics are suited. Ordinarily, fabrics are manufactured so as to exhibit a “machine direction” (MD), extending along the length of the fabric in the direction in which it is manufactured, and a “cross-direction” (CD) extending perpendicularly to the machine direction. While fabrics can be engineered to exhibit certain properties, these fabrics ordinarily do not exhibit a relatively high degree of recovery, after extension, in the cross-direction.
Another type of manufactured product, which is finding widespread applications are leather-like laminates typically formed by application of an elastomeric or other polymeric composition to a fibrous substrate, which may comprise a woven or nonwoven fabric. Like the above-described nonwoven fabrics, these types of stretchable laminates can be readily engineered to exhibit desired physical properties, including extensibility and recovery and water resistance, and can be formed to provide an aesthetically pleasing texture and appearance.
SUMMARY OF THE INVENTION
The present invention is directed to a stretchable laminate formed by applying an elastomeric composition to a nonwoven fabric exhibiting cross-direction extensibility and recovery. A leather-like product exhibiting a high degree of conformability, and aesthetically pleasing texture and appearance is thus achieved.
The hydroentangled (spun-laced) nonwoven fabric, which forms the substrate of the present laminate has been particularly configured to exhibit elastic characteristics, that is, extensibility and recovery, in the cross-direction of the fabric. The cross-direction (CD) is transverse or perpendicular to the machine-direction (MD) of the fabric, that is, the direction in which the fabric is manufactured and processed, typically extending along the longitudinal axis of the fabric. By configuring the present fabric to exhibit cross-direction elasticity, the fabric can be employed in those applications in which such elastic characteristics are desirable.
A nonwoven fabric for use in the present invention comprises a hydroentangled nonwoven web preferably comprising staple length textile fibers of about 0.8 to 3.0 denier having a basis weight of about 1.0 to 6.0 ounces per square yard, preferably 2.0 to 4.0 ounces per square yard. More preferably, the nonwoven web comprises fibers of about 1.5 denier, with the web having a basis weight of about 2.5 to 3.5 ounces per square yard. Use of polyester fibers is presently preferred, but it is within the purview of the present invention to form the present nonwoven fabric from blends, which include at least a portion of synthetic fibers blended with natural fibers, and from substantially continuous filaments.
The nonwoven web is subjected to hydroentanglement in order to entangle and integrate the fibers of the web, and thus lends integrity to the structure. In a current preferred embodiment, hydroentanglement is effected so as to impart a rectilinear pattern to the nonwoven web, which pattern is preferably oriented at an angle between about 30° and 60° relative to a machine-direction of the web. In a preferred method of formation, the nonwoven web is subjected to preliminary hydroentanglement to lend integrity thereto prior to formation of the rectilinear pattern in the web by hydroentanglement on a patterned forming surface.
In order to impart elastomeric characteristics to the fabric formed by hydroentanglement, a polymeric binder composition is substantially uniformly applied to the nonwoven fabric. Although the specific amount of binder can be varied while keeping with the principles disclosed herein, it is presently preferred that the binder composition comprise between about 17% and about 31%, by weight, of acrylic binder. Subsequent to application of the polymeric binder composition, the nonwoven web is dried to form the nonwoven fabric, which provides the substrate of the present stretchable laminate. Significantly, the resultant nonwoven fabric exhibits elastomeric characteristics (i.e., stretch or extensibility, and recovery) in the cross-direction of the fabric. In accordance with the present invention, the fabric exhibits at least about 20% extensibility in the cross-direction, and at least about 90% recovery in the cross-direction, preferably at least about 50% extensibility in the cross-direction, with at least about 90% recovery. The fabric is thus engineered to exhibit a relatively high degree of cross-direction elasticity.
In order to form the stretchable laminate embodying the principles of the present invention, the above-described nonwoven fabric is coated with an elastomeric composition, which composition is selected from the group consisting of polyurethane and polyvinylchloride (PVC). The nonwoven fabric substrate can be covered with a layer of the elastomeric coating, with the coating having a thickness of about 0.020 inches to 0.125 inches. The resultant stretchable laminate exhibits leather-like characteristics, and is highly conformable, thus facilitating its use for apparel, upholstery, and footwear.
Other features and advantages of the present invention will become readily apparent from the following detailed description, the accompanying drawings, and the appended claims.


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patent: 6299977 (2001-10-01), Takeyama et al.
patent: PCT/US02-04795 (2002-07-01), None
patent: PCT/US02-04795 (2002-11-01), None

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