Stratified fibrous fluoropolymer compositions and process for fo

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525902, C08F25908

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048597457

ABSTRACT:
The invention is a process for producing a modified polytetrafluoroethylene which comprises polymerizing tetrafluoroethylene in an aqueous medium containing a dispersing agent with a polymerization initiator source and then, copolymerizing tetrafluoroethylene one or more fluorinated modifiers having an acid functional group or a functional group which is convertible to the acid group as a copolymerizable modifier in the presence of the resulting polytetrafluoroethylene to a polymerization point past the Kraft point to produce highly porous, fibrous, stratified fluoropolymers having cores made of homopolymer of poly-tetrafluoroethylene coated with sheath layers which are made of a copolymer of polytetrafluoroethylene and one or more modifiers.
The invention also includes a highly porous, fibrous, stratified fluoropolymer having a plurality of interconnected, fibrous-like projections wherein the stratified fluoropolymer has a core layer of polytetrafluoroethylene substantially completely covered by a copolymer of polytetrafluoroethylene and a fluorocarbon modifier.

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