Electricity: measuring and testing – Electrolyte properties – Using a conductivity determining device
Reexamination Certificate
1999-12-08
2002-06-18
Le, N. (Department: 2858)
Electricity: measuring and testing
Electrolyte properties
Using a conductivity determining device
C324S427000, C073S720000, C073S726000, C429S090000
Reexamination Certificate
active
06407553
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates generally to the field of electric batteries, and more specifically, to determining charge levels in a battery having a thin walled pressure vessel. These types of batteries are used in low earth orbit (LEO) spacecraft or satellites. Strain gages are installed on the pressure vessels, using adhesives, at predetermined locations and provide an output that varies in accordance with battery charge.
DESCRIPTION OF THE RELATED ART
A spacecraft orbiting the earth requires energy storage batteries to power system loads when the orbital path is in the shadow of the earth. In sunlight, solar arrays power system loads and recharge the batteries. A typical orbit time for a spacecraft in a low earth orbit is 90 minutes, with about two-thirds of the time in sunlight and one-third in shadow. This works out to approximately 5,800 cycles per year.
By way of example,
FIG. 1
schematically illustrates a satellite
10
and one of its battery bays
12
, and showing exposure to the sun
14
. On the HST satellite, the bay
12
contained three batteries; all batteries carried by the satellite were nickel-cadmium (NiCd), but subsequently, NiH
2
cells and batteries were developed to extend operational life.
It is desirable to have batteries fully charged for maximum available reserve power; however, any overcharge is dissipated as heat. Excess heat upsets the thermal balance of the spacecraft, puts extra loading on the thermal radiators, and causes the batteries to heat, all of which is undesirable. The batteries are initially efficient and generate very little heat during charging to about 90% of full capacity.
Methods used to control charging of the batteries include time-rate ampere hour integration control and/or battery voltage sensing to maintain state-of-charge of the battery. An on-board computer can be used to control the charge rate and cut off to prevent overcharge. This arrangement has worked well, except when the computer malfunctions, requiring it to be reset and re-initialized. One of the features of the NiH
2
battery is a relatively flat discharge voltage profile over a large range of capacity. This requires an estimate of the state-of-charge to be loaded into the computer to regain charge control.
The Hubble Space Telescope was the first LEO application for a NiH
2
battery system, and it has operated successfully since launch in 1990. The Hubble Space Telescope spacecraft has six (6) eighty-eight (88) ampere-hour batteries, which were manufactured by Eagle Picher Technologies, LLC. Reasons for choosing the NiH
2
batteries include lower weight (the NiH
2
batteries weight 120 pounds, versus about 180 pounds for the NiCd batteries) and a projected life of twelve (12) years versus three (3) to four (4) years for the NiCd batteries.
The NiH
2
cell generates hydrogen gas and, as it charges in the closed container, the amount of gas is proportional to the amount of charge in the cell. The internal pressure of a battery cell varies from about fifteen (15) psia at full discharge to over 1,000 psia at full charge. This can provide a convenient way to determine actual state-of-charge of the cell similar to that of a fuel gauge on a car. Moreover, it is not dependent on time-rate integration of the computer and can be used for charge control and cut-off
Referring to
FIG. 2
, each battery cell container
16
is a thin-walled shell made of a strong metallic material, such as INCONEL having a wall thickness of approximately 0.030 to 0.040 inches, in the form of a pressure vessel having a diameter of 3.5 inches and an overall length of about 10.5 inches. Each container
16
has a cylindrical medial portion
18
and two opposite axial dome shaped end portions
20
and
22
, having hemispherical shapes, which are integrally formed with the cylindrical portion
18
.
Strain gauges have been used in the past on battery cells to measure state-of-charge. They provide an attractive, non-intrusive, non-invasive method for the measurement of cell pressure, and thus, state-of-charge. Two or more cells in each battery have strain gauges installed as a primary and back up state-of-charge indicators. Referring to
FIG. 3
, a strain gauge system used on the Hubble Space Telescope installations is shown as a top view of one of the domed ends of the container
16
. The illustration is of a full bridge configuration with two active legs or strain gauges
24
and
26
installed on the domed-shaped end
22
of the cell. Two inactive strain gauges
28
and
30
are installed on an unstrained metal coupon
32
(cut from another dome section) and bonded to the domed end
22
near the active strain gauges
24
and
26
with an adhesive, such as RTV 566. A multi-layer flexible circuit
34
is used with soldered wire jumpers to interconect the gauges. The system includes a bridge balance resistor
36
.
The gauges are Micromeasurements model CEA-06-250-350, constantan grid, encapsulated in a polyimide envelope, which are installed with M-bond 610 adhesive.
The completed cell with gauge installation is then coated with “Conathane” that serves as an insulator and a protective coating. A retrofit of strain gauges on completed cells required an adhesive with a much lower cure temperature than required for the 610 adhesive. M-bond AE15 was found to be suitable. This adhesive was also used by Gates Aerospace with type WK gauges for installation on their space flight cells.
A complete battery assembly with strain gauge bridges on two cells, substantially of the construction described above, was installed in a vacuum chamber for a thermal/vacuum test. The battery was charged and discharged at different stabilized temperatures. Strain gauges were monitored and recorded during the test in order to study power dissipation from the strain gauges in addition to the thermal performance characteristics of the battery. During testing, temperature changes when the battery was not operated, i.e., in steady-state, the indicated pressure shift from the strain gauges was not as predicted due to test temperature changes. In fact, readings changed by a larger amount and in the opposite direction.
It was determined that there was insufficient test data to establish any thermal zero shift for the strain gauge bridges, and there were no tests run in a vacuum chamber for production “end item” batteries. In a vacuum chamber, to simulate the condition of use, the transfer path is much different than atmospheric conditions. Half of the heat dissipated from the strain gauge bridge circuit is on the metal coupon.
In a vacuum, no convection transfer takes place, radiation transfer is minimal and the heat from the coupon must conduct through the attachment to the cell, through the cell to support thermal sleeve and to the base plate. The thermal test showed that the cells with strain gauges were a few degrees warmer than cells without gauges. The corollary of this is that the coupon with the two compensation gauges must be a few degrees warmer than the cell to transfer the heat to the cell, and therefore, any temperature related effects on the zero reference, including thermoelectric effects, are increased. Thus, the larger the excitation, the greater the dissipation and the greater the zero shift problem. Fabricators of other NiH
2
cells use a similar bridge installation with two inactive (compensation) gauges on a coupon. Although the selected gauges and adhesives vary, most applications may experience similar zero shifts under actual conditions of use.
End item users would prefer an accuracy within +/−15% FSO or better for the measurement. Estimated error for existing systems can be as high as +/−15%. Cycle to cycle repeatability is fairly good, although it can drift with temperature. The on-board calibration to verify system/amplifier/excitation integrity is not included. The only way users can gain some confidence and re-establish a baseline is to perform a complete capacity check, where the battery is discharged through a resistor to a very low terminal voltage (alm
Anderson Duane Selwyn
Armantrout Jon David
Cuzner Gregor Jon
Deb Anjan K.
Lockhead Martin Corporation
Swidler Berlin Shereff & Friedman, LLP
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