Stereoselective process for enalapril

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D20708

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active

060255005

ABSTRACT:
The invention relates to an improved stereoselective heterogenous catalytic reductive amination between ethyl 2-oxo-4-phenylbutyrate and alanylproline using hydrogen, a catalyst and one or more additives to produce the ACE inhibitor, enalapril.

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Blacklock et al, "Synthesis of Semisynthetic Dipeptides Using N-Carboxyanhydrides and Chiral Induction on raney Nickel", J. Org. Chem., 1988, 53, 836-844.

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