Stereoselective introduction of tetracyclines hydroxyl group at

Details Stereoselective introduction of tetracyclines hydroxyl group at Stereoselective introduction of tetracyclines hydroxyl group at

1972-12-29

1976-03-30

Daus, Donald G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260240F, 2603067R, 2603406, 260473F, 260482R, 260483, 260590FB, C07C10319

Patent

active

039475174

ABSTRACT:
In the synthesis of tetracyclines, a critical step is the stereospecific or stereoselective introduction of a hydroxyl group at the C-12(a) position, a novel method for the introduction of this critical hydroxy group is disclosed. Additionally, synthetic procedures for obtaining tetracycline precursors are discussed.

REFERENCES:
patent: 3188348 (1965-06-01), Butler et al.

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