Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1995-10-19
1997-08-19
Killos, Paul J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568697, 568698, 568909, C07C 4100
Patent
active
056590903
ABSTRACT:
The invention concerns steps in a process for the synthesis of at least one alkyl tertiobutyl ether, preferably respectively MTBE or ETBE, from at least one alcohol and from isobutene, each synthesized at least partially from natural gas. The alcohol, preferably methanol or ethanol respectively, is synthesized at least partially from synthesis gas, a portion of said synthesis gas being prepared in a natural gas steam prereforming zone. The isobutene is synthesized in a series of processes which includes direct transformation of natural gas to ethylene, known as oxidative coupling of methane (OCM), dimerisation of ethylene to normal butene, isomerisation of n-butene to isobutene, and the separation units associated therewith.
REFERENCES:
patent: 4731490 (1988-03-01), Coughenour et al.
J. Foreman, "Adding Another Step to Steam Reforming Aves Fuel and . . . ", Hydrocarbon Processing, vol. 69 (12):34B-34D, Dec. 1990.
Bousquet Jacques
Cameron Charles
Chaumette Patrick
Dang Vu Quang
Desgrandchamps Guy
Elf Aquitaine Production
Institut Francais du Pe'trole
Killos Paul J.
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