Metal treatment – Stock – Magnetic
Reexamination Certificate
2001-03-09
2003-05-13
Sheehan, John (Department: 1742)
Metal treatment
Stock
Magnetic
C148S111000, C148S120000
Reexamination Certificate
active
06562150
ABSTRACT:
TECHNICAL FIELD
The present invention relates to a steel sheet for heat shrink band which tightens the panel of cathode-ray tube (CRT) used in color television, computer monitor and the like, and to a manufacturing method of it.
BACKGROUND ART
Since CRTs are evacuated into a high vacuum of about 1×10
−
Torr, the deformation of a panel surface and the internal explosion of a tube must be prevented. For this purpose, so-called heat shrinking treatment is executed in the following manner. That is, a heat shrink band composed of a steel sheet formed to a band shape is heated and expanded in the temperature range of about 400 to 600° C. for several seconds to several tens of seconds, put over the panel of a CRT, and then cooled and shrunk.
Further, since the heat shrink band has a function for shielding the geomagnetism similarly to the internal magnetic shield, it prevents the occurrence of landing error of electron beams on the surface of a fluorescent layer, that is, the occurrence of color deviation which is caused by the geomagnetism.
Conventionally, plated mild steel sheets have been used as a material of heat shrink band. However, since the magnetic permeability of the mild steel at the level of the geomagnetism (about 0.3 Oe) is about 200 so that it is not sufficient for the magnetic shielding performance, troublesome processes such as the adjustment of the position of a fluorescent layer, and the like are required in order to prevent the color deviation caused by the geomagnetism. Current CRTs have, therefore, an alternate current demagnetization circuit to improve the magnetic shielding performance.
Along with the increase in size of television screen in recent years, the heat shrink band is requested to have sufficient strength to prevent the deformation of a panel surface. To meet the requirement, the strength of steel sheet for heat shrink band has increased. The increase in strength, however, degrades the magnetic shielding performance, and the color deviation caused by geomagnetism has become more and more significant.
Japanese Patent Laid-Open No. 208670(1998) discloses a steel sheet for heat shrink band wherein both the strength and the magnetic performance are improved by adding 2 to 4% Si to a very low carbon steel of not higher than 0.005% C, and a manufacturing method of it.
However, when we actually applied the steel sheet for heat shrink band disclosed in Japanese Patent Laid-Open No. 10-208670 to color CRTs, a sufficient magnetic shielding performance could not be always obtained. Further, since the steel sheet contains much Si, the oxidized Si formed on the surface of a steel sheet contaminates the annealing line, and degrades the production yield.
DISCLOSURE OF THE INVENTION
An object of the present invention, which was made to solve these problems, is to provide a steel sheet for heat shrink band having a magnetic shielding performance capable of reliably preventing the color deviation and a strength enough for preventing the deformation of a large panel surface, and a manufacturing method of it.
The above object can be achieved by a steel sheet for heat shrink band having anhysteretic magnetic permeability of 15,000 or higher at 0.35 Oe and yield stress of 24 kgf/mm
2
or more.
The steel sheet for heat shrink band can be manufactured by a method comprising the steps of: hot rolling and/or cold rolling a steel containing 0.01 to 0.15% C by weight; annealing the rolled steel sheet at a temperature ranging from 650 to 900° C.; and temper rolling the annealed steel sheet at a rolling reduction rate of 1.5% or less, or by a method comprising the steps of: hot rolling and/or cold rolling a steel containing 0.01 to 0.15% C by weight; annealing the rolled steel sheet at a temperature ranging from 650 to 900° C.; overaging the annealed steel sheet at a temperature ranging from 250 to 500° C.; and temper rolling the overaged steel sheet at a rolling reduction rate of 1.5% or less.
BEST MODE FOR CARRYING OUT THE INVENTION
Generally, it is known that the magnetization of material after demagnetization in a direct current magnetic field converges to an anhysteretic magnetization (or ideal magnetization) responding to the direct current magnetic field. The slope of the anhysteretic magnetization (magnetic flux density) to the direct current magnetic field is called “anhysteretic magnetic permeability”.
We investigated the relationship between geomagnetic shielding performance and anhysteretic magnetic permeability at a direct current bias magnetic field of 0.35 Oe on steel sheets having various kinds of chemical composition. The anhysteretic magnetic permeability was measured in the following procedure.
i) A ring-shaped specimen wound with an excitation coil, a detection coil and a direct current bias magnetic field coil is completely demagnetized by supplying an attenuating alternate current to the excitation coil.
ii) A direct current is supplied to the bias magnetic field coil to generate a direct current magnetic field of 0.35 Oe. In this state, again the attenuating alternate current is supplied to the excitation coil to demagnetizing the specimen.
iii) In a state of applying the bias magnetic field, the B-H loop (hysteresis loop) is measured at the maximum applied field of 40 Oe.
iv) The anhysteretic magnetic permeability is determined from the asymmetry of the B-H loop.
As a result, the following findings are obtained.
1) The anhysteretic magnetic permeability does not necessarily give similar behavior with the magnetic permeability at geomagnetism level which is a normal reference level of evaluation. Geomagnetic shielding performance can be achieved owing to the high anhysteretic magnetic permeability even if the normal magnetic permeability is low. The anhysteretic magnetic permeability of current steel sheets for heat shrink bands ranges from 7000 to 13000.
2) The anhysteretic magnetic permeability has better correlation with the preventive effect of color deviation of cathode ray tubes after alternate current demagnetization, i.e., after the degaussing process, than the normal magnetic permeability.
3) By adopting a steel sheet having anhysteretic magnetic permeability of 15,000 or higher and yield stress of 24 kgf /mm
2
or more, the improvement in earth magnetic shielding performance is attained while securing sufficient strength.
4) To increase the anhysteretic magnetic permeability, it is very effective that a steel contains 0.01 to 0.15% C, that the steel is annealed at a temperature ranging from 650 to 900° C., and that the steel is temper rolled at a rolling reduction rate of 1.5% or less (including no temper rolling).
Excessively large coercive force of a steel sheet fails to attain sufficient demagnetization of the steel sheet during the degaussing process, and the magnetization in the direction of geomagnetism fails to reach the anhysteretic magnetization level, which results in degradation of shielding performance. Therefore, considering that the practical maximum magnetism generated by the demagnetization circuit is several Oe, the upper limit of the coercive force is preferably specified to 5 Oe or less. The anhysteretic magnetic permeability has close relation with the magnitude of remanent magnetic flux density. It is desirable for the remanent magnetic flux density to be 10 kG or more in order that the anhysteretic magnetic permeability surely becomes 15,000 or higher.
Different from the ordinary magnetic permeability, the anhysteretic magnetic permeability improves with carbon content. When the carbon content is 0.01% or more, the anhysteretic magnetic permeability always becomes 15,000 or more. If, however, the carbon content exceeds 0.15%, the coercive force tends to exceed 5 Oe, which results in degradation of the magnetic shielding performance. Therefore, the limit of carbon content is preferably specified to 0.01 to 0.15%.
The steel sheet for heat shrink band of the present invention can be manufactured, for example, by hot rolling and/or cold rolling a steel containing 0.01 to 0.15% C by weight, annealing the rolled stee
Hiratani Tatsuhiko
Matsuoka Hideki
Sugihara Reiko
Tanaka Yasushi
Frishauf Holtz Goodman & Chick P.C.
NKK Corporation
Sheehan John
LandOfFree
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