Steam-hydrocarbon process

Compositions – Gaseous compositions – Carbon-oxide and hydrogen containing

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48196A, 48214A, C01B 216

Patent

active

040726258

ABSTRACT:
In a process of reacting a hydrocarbon with steam and/or carbon dioxide in a reaction zone heated by a combustion furnace to give olefins or process gas containing carbon oxides and hydrogen high grade heat is recovered from furnace flue gases and/or process gas whereby to cool such gases to 150-300.degree. C. When the process gas is used in a synthesis of for example methanol or ammonia, gases at 150.degree.-300.degree. C are also produced. Previously the recovery of heat from such low grade heat sources has been inefficient or inconvenient. According to the invention the heat is recovered by means of an intermediary liquid coolant, which is brought into direct heat exchange with streams to be used in the process. Preferably the liquid is water under pressure and is brought into direct heat exchange with a gas to be fed to the process; by this means 10-30% of the steam can be provided from low grade waste heat.

REFERENCES:
patent: 2870096 (1959-01-01), Baumann
patent: 3088919 (1963-05-01), Brown et al.
patent: 3136624 (1964-06-01), Made et al.
patent: 3150931 (1964-09-01), Frank
patent: 3441393 (1969-04-01), Finneran et al.
patent: 3743488 (1973-07-01), Bogart
patent: 3898057 (1975-08-01), Moller
"Heat Recovery in Ammonia Plants," Silberring, pp. 74-76, CPE Heat Transfer Survey, 1969.
"Operating Performance of 57-3 on the ICI 100 Atmospheres Methanol Plant," Cornell, ICI Catalyst Customers Conf. 1975.

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