Steam dehydrogenation process

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By dehydrogenation

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Details

585661, 208137, 208138, C07C 5333, C10G 3506

Patent

active

052331180

ABSTRACT:
A process for the steam dehydrogenation of hydrocarbons which utilizes a novel catalytic composition is disclosed. The catalyst composite comprises a Group VIII noble metal component, a Group IA or IIA metal component, and a component selected from the group consisting of tin, germanium, lead, indium, gallium thallium, or mixtures thereof, all on an essentially theta-alumina support having a surface area of from about 50 to 120 m2/g, and an Apparent Bulk Density of 0.5 g/cm3 or more. The process is performed at a water to hydrocarbon molar ratio of 0.25:1 to 10:1.

REFERENCES:
patent: 4048099 (1977-09-01), Hayes
patent: 4070413 (1978-01-01), Imai
patent: 4608360 (1986-08-01), Abrevaya et al.
patent: 4717779 (1988-01-01), Bricker et al.
patent: 4786625 (1988-11-01), Imai et al.
patent: 4788371 (1988-11-01), Imai et al.

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