Starch-polyester biodegradable graft copolymers and a method...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C523S128000, C524S018000, C524S047000, C524S386000, C524S387000, C524S447000, C524S449000, C525S054240, C527S300000, C527S305000, C527S315000

Reexamination Certificate

active

07985794

ABSTRACT:
A starch-polyester graft copolymer and chemically modified starch-polyester graft copolymer composition comprising a chemically modified starch or chemically modified starch-nanoclay product is described. The composition can be produced continuously in a twin-screw co-rotating extruder. The starch-polyester graft copolymer can be solvent cast, melt cast and blown into clear transparent film particularly for use in single use disposable applications and can be biodegradable.

REFERENCES:
patent: 4026849 (1977-05-01), Bagley et al.
patent: 4673438 (1987-06-01), Wittwer
patent: 4863655 (1989-09-01), Lacourse et al.
patent: 5035930 (1991-07-01), Lacourse et al.
patent: 5043196 (1991-08-01), Lacourse et al.
patent: 5095054 (1992-03-01), Lay et al.
patent: 5185382 (1993-02-01), Neumann et al.
patent: 5208267 (1993-05-01), Neumann et al.
patent: 5234977 (1993-08-01), Bastioli et al.
patent: 5256711 (1993-10-01), Tokiwa et al.
patent: 5262458 (1993-11-01), Bastioli et al.
patent: 5272181 (1993-12-01), Boehmer et al.
patent: 5275774 (1994-01-01), Bahr et al.
patent: 5280055 (1994-01-01), Tomka
patent: 5288765 (1994-02-01), Bastioli et al.
patent: 5314934 (1994-05-01), Tomka
patent: 5360830 (1994-11-01), Bastioli et al.
patent: 5382611 (1995-01-01), Stepto et al.
patent: 5405564 (1995-04-01), Stepto et al.
patent: 5412005 (1995-05-01), Bastioli et al.
patent: 5462980 (1995-10-01), Bastioli et al.
patent: 5462983 (1995-10-01), Bloembergen et al.
patent: 5496895 (1996-03-01), Chinnaswamy et al.
patent: 5500465 (1996-03-01), Krishnan et al.
patent: 5512378 (1996-04-01), Bastioli et al.
patent: 5540929 (1996-07-01), Narayan et al.
patent: 5554660 (1996-09-01), Altieri et al.
patent: 5578691 (1996-11-01), Narayan et al.
patent: 5616671 (1997-04-01), Narayan et al.
patent: 5665786 (1997-09-01), Xu et al.
patent: 5719214 (1998-02-01), Tanaka et al.
patent: 5736586 (1998-04-01), Bastioli et al.
patent: 5801207 (1998-09-01), Bastioli et al.
patent: 5844023 (1998-12-01), Tomka
patent: 5854345 (1998-12-01), Xu et al.
patent: 5861461 (1999-01-01), Lee et al.
patent: 5869647 (1999-02-01), Narayan et al.
patent: 6011092 (2000-01-01), Seppala et al.
patent: 6124384 (2000-09-01), Shiraishi et al.
patent: 6150438 (2000-11-01), Shiraishi et al.
patent: 6184261 (2001-02-01), Biby et al.
patent: 6214907 (2001-04-01), Tomka
patent: 6235816 (2001-05-01), Loercks et al.
patent: 6277899 (2001-08-01), Bastioli et al.
patent: 6472497 (2002-10-01), Loercks et al.
patent: 7153354 (2006-12-01), Narayan et al.
patent: 7629405 (2009-12-01), Narayan et al.
patent: 2001/0014388 (2001-08-01), Bastioli et al.
patent: 2004/0122135 (2004-06-01), Halley et al.
W. Wiedmann, and E. Strobel, “Compounding of Thermoplastic Starch with Twin-screw Extruders”, Starch, 43, 138-145 (1991).
R.L. Shorgen, G.F. Fanta, and W.M. Doane, “Development of Starch Based Plastics—A Reexamination of Selected Polymer Systems in Historical Perspective”, Starch, 45, 276-280 (1993).
P. Forssell, J. Mikkila, and T. Suortti, “Plasticization of Barley Starch with Glycerol and Water”, J.M.S. Pure Appl. Chem. A33(5), 703-715 (1996).
R. Narayan, “Polymeric Materials from Agricultural Feedstocks”, ACS Symp Ser. (1994).
J.J.G. van Soest, K. Benes, and D. deWit, “The influence of starch molecular mass on the properties of extruded thermoplastic starch”, Polymer, 37, 3543-3552 (1996).
G.F. Fanta and E.B. Bagley, “Starch, Graft Copolymers”, Encyclopedia of Polymer Science, John Wiley & Sons: New York, 665-699 (1970).
G.F. Fanta, “Synthesis of Graft and Block Copolymers”, Block and Graft Copolymerization—vol. I, John Wiley & Sons: New York, 1-45 (1973).
F.H. Otey, R.P. Westhoff and W.M. Doane, “Starch-based blown films”, ACS Ind. Eng. Chem. Prod. Res. Dev., 19, 592-595 (1980).
F.H. Otey and R.P. Westhoff, “Strach-based films. Preliminary diffusion evaluation”, ACS Ind. Eng. Chem. Prod. Res. Dev., 23, 284-287 (1984).
F.H. Otey, R.P. Westhoff and W.M. Doane, “Strach-based blown films. 2”, ACS Ind. Eng. Chem. Prod. Res. Dev., 26, 1659-1663 (1987).
“Starch: Chemistry and Technology” Chapter XIII (H. Roberts, “Starch Derivatives”), and Chapter XV (L. Kruger et al., “Production and Uses of Starch Acetates”), Academic Press (1967).
“Encyclopedia of Polymer Science and Engineering”, vol. 6, 1986, pp. 571-631.
“Starch: Chemistry and Technology”, Chapter X (M.W. Rutenberg, and D. Solarek, “Starch Derivatives: Production and Uses”), Academic Press, Inc. (1984).
Bhattacharya M., Vaidya U.R., Zhang D., and Narayan R., Journal of Applied Polymer Science, 57: 539 (1995).
Tuil R.V., Fowler, P., Lawrher, M., and Weber, C.J., “Properties of biobased packaging materials”, in: Biobased Packaging Materials for the Food Industry—Status and Perspectives, ed. Claus J. Weber, p. 12, Nov. 2000.
Kalambur S. and Rizvi S.S.H., “An Overview of Starch-Based Plastic Blends from Reactive Extrusion”, Journal of Plastic Film & Sheeting, vol. 22, Jan. 2006.
Averous L., Fringant C., and Moro L., “Starch-based Biodegradable Materials Suitable for Thermoforming Packaging”, Starch/Starke, 53: 368-371 (2001).
Zobel H.F., “Molecules to granules: a comprehensive starch review”, Starch/Starke, 40(2): 44-50 (1988).
Van Soest, J.J.G., Knooren, N., “Influence of Glycerol and Water Content on the Structure and Properties Extruded Starch Plastic Sheets During Aging”, Journal of Applied Polymer Science, 64: 1411-1422 (1997).
Vaidya U.R. and Bhattacharya M., Journal of Applied Polymer Science, 52: 617-628 (1994).
Mani R. and Bhattacharya M., European Polymer Journal, 34: 1467-1475 (1998).
Carlson, D.L., Nie, L., Narayan, R., Dubois, P., Journal of Applied Polymer Science, 72: 477-485 (1999).
Wu, C-S., “Physical properties and biodegradability of maleated-polycaprolactone/starch composite”, Polymer Degradation and Stability, 80: 127-134 (2003).
Nabar Y., Raquez J.M., Dubois P., Narayan R., “Production of starch foams by twin-screw extrusion: Effect of maleated poly(butylene adipate-co-terephthalate) as a compatibilizer”, Biomacromolecules, 6: 807-817 (2005).
Dubois P. and Narayan R., “Biodegradable Compositions by Reactive Processing of Aliphatic Polyester/Polysaccharide Blends”, Macromolecular Symposia, 198: 233-243 (2003).
Huneault M.A. and Li H., “Morphology and Properties of compatibilized polylactide/thermoplastic starch blends”, Polymer, 48: 270-280 (2007).
Chandra R. and Rustgi R., “Biodegradation of maleated linear low-density polyethylene and starch blends”, Polymer Degradation and Stability, 56: 185-202 (1997).
Shujun W., Jiugao Y., and Jinglin Y., “Preparation and characterization of compatible thermoplastic starch/polyethylene blends”, Polymer Degradation and Stability, 87: 395-401 (2005).
Rindlav-Westling A., Stading M., Hermansson A.M. & Gatenholm P., “Structure, mechanical and barrier properties of amylose and amylopectin films”, Carbohydrate Polymers, 36: 217-224 (1998).
Lourdin D., Della Valle G., Colonna P., “Influence of amylose content on starch films and foams”, Carbohydrate Polymers, 27: 261-270 (1995).
Tharanathan R.N., “Biodegradable films and composite coatings: past, present and future”, Trends in Food Science and Technology, 14: 71-78 (2003).
Alves V.D., Mali S., Grossmann M.V., and Beleia A., “Effect of glycerol and amylose enrichment on cassava starch, film properties”, Journal of Food Engineering, 78(3): 941-946 (2007).
Myllarinen P., Partanen R., Seppala J., and Forssell P., “Effect of glycerol on behavior of amylose and amylopectin films”, Carbohydrate Polymers, 50: 355-361 (2002).
Mali S., Grossmann M.V.E., Garcia M.A., Martino M.N., and Zaritzky N.E., “Microstructural characterization of yam

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Starch-polyester biodegradable graft copolymers and a method... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Starch-polyester biodegradable graft copolymers and a method..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Starch-polyester biodegradable graft copolymers and a method... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-2648872

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.