Stabilization of polymeric acetal carboxylates using an acetal

Details Stabilization of polymeric acetal carboxylates using an acetal Stabilization of polymeric acetal carboxylates using an acetal

1979-11-05

1980-11-11

Phynes, Lucille M.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

528232, 528489, 528494, C08G 600, C08L 6102

Patent

active

042334233

ABSTRACT:
The alkali metal, ammonium and alkanol amine salts of polymeric acetal carboxylates are stable detergent builders and chelating agents. Now, in the improved process of the present invention for preparing an acetal carboxylate polymer wherein a glyoxylate ester and a polymerization initiator are brought together under polymerization conditions and a chemically stable end group is added to the termini of the resulting polymer to stabilize the polymer against rapid depolymerization in alkaline solution, the improvement comprises contacting the resulting polymer in the presence of an acid catalyst with a sufficient amount of an acetal having 3 to 20 carbon atoms to stabilize the resulting polymer against rapid depolymerization in alkaline solution, and an agent to remove liberated alcohol.

REFERENCES:
patent: 4140676 (1979-02-01), Crutchfield et al.
patent: 4144226 (1979-03-01), Crutchfield et al.
patent: 4146495 (1979-03-01), Crutchfield et al.

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