Spring steel superior in fatigue properties

Metal treatment – Stock – Ferrous

Reexamination Certificate

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Details

C148S540000, C148S908000, C148S333000, C420S105000

Reexamination Certificate

active

06328820

ABSTRACT:

BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a spring steel superior in fatigue properties. More particularly, the present invention relates to a spring steel (for valve springs and the like) superior in fatigue properties which is characterized by a low content of undeformable inclusions.
2. Description of the Related Art
It is a well-known fact that such steels as used for valve springs, which need a high fatigue strength, are liable to fracture that starts from hard non-metallic inclusions if they contain them. In order to prevent fracture due to such hard inclusions, there have been proposed several ways to control their composition such that they have a melting point lower than 1500° C. Such hard inclusions are made smaller by hot or cold rolling or drawing.
There is disclosed a steel with a high degree of cleanliness in Japanese Patent Publication No. 74484/1994. This steel contains non-metallic inclusions whose average composition is SiO
2
: 20~60%, MnO: 10~80%, and CaO: 13~50%, and/or MgO: 5~15%. These non-metallic inclusions are characterized by that the ratio of length (l) to width (d) measured in the longitudinal cross-section of rolled steel is l/d≦5. There is also disclosed a steel with a high degree of cleanliness in Japanese Patent Publication No. 74485/1994. This steel contains non-metallic inclusions whose average composition is SiO
2
: 35~75%, MnO: Al
2
O
3
: ≦30%, CaO: 10~50%, and MgO: 3~25%. These non-metallic inclusions are characterized by that the ratio of length (l) to width (d) measured in the longitudinal cross-section of rolled steel is l/d≦5.
The steels with a high degree of cleanliness disclosed in the above-mentioned patents are designed to improve the fatigue properties by controlling the average composition of non-metallic inclusions such that the ratio of length (l) to width (d) is l/d≦5. The present inventors found that they have the following problems.
Even though the average composition of non-metallic inclusions is controlled so that l/d≦5, there still exist hard inclusions exceeding this limit and they cause breakage. Moreover, even though inclusions are ductile and satisfy the condition l/d≦5, they also cause breakage if they are thick.
OBJECT AND SUMMARY OF THE INVENTION
The present invention was completed in order to tackle the above-mentioned problems. It is an object of the present invention to provide a spring steel superior in fatigue properties.
The gist of the present invention resides in a spring steel superior in fatigue properties which is characterized in that oxide type inclusions therein have an average composition (by weight) specified as follows:
35%≦SiO
2
≦75%
5%≦Al
2
O
3
≦30%
10%≦CaO≦50%
MgO≦5% (excluding 0%)
According to a preferred embodiment of the invention, the spring steel is characterized in that oxide type inclusions thinner than 5 &mgr;m account for more than 80% (in number) of total oxide type inclusions in the longitudinal cross-section of rolled steel.
Moreover, for improved fatigue properties, the spring steel should be produced such that its surface defects have a depth less than 1.0% of its diameter and its total decarburized depth is less than 1.0% of its diameter.


REFERENCES:
patent: 5415711 (1995-05-01), Takagi et al.
patent: 5651937 (1997-07-01), Descaves
patent: 6123784 (2000-09-01), Havette
patent: 1 010 769 (2000-06-01), None
patent: 62-099437 (1987-05-01), None
patent: 02-034748 (1990-02-01), None
patent: 04-006211 (1992-01-01), None
patent: 06-145895 (1994-05-01), None
patent: 06-158226 (1994-06-01), None
Patent Abstracts of Japan, vol. 1998, No. 09, Jul. 13, 1998, JP 10-102131, Apr. 21, 1998.
Chemical Abstracts, vol. 112, No. 2, Jan. 8, 1990, AN 10285, T. Ohshiro, et al., “Improvement of the Service Life of Valve Spring Wire”, 1989.

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