Spontaneously-formed celsian glass-ceramics

Glass manufacturing – Processes – Devitrifying glass or vitrifying crystalline glass

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106 398, C03B 3200, C03C 322

Patent

active

039855325

ABSTRACT:
The instant invention relates to the production of articles exhibiting the physical properties and internal microstructure of glass-ceramic materials but which can be formed spontaneously from a molten glass, i.e., no heat treatment of a glass body to cause the crystallization in situ thereof is required, as is demanded in the manufacture of conventional glass-ceramic articles. More specifically, this invention is concerned with the production of glass-ceramic articles having compositions within the BaO-Al.sub.2 O.sub. 3 -SiO.sub.2 -F field which, when nucleated with TiO.sub.2, contain celsian (BaO.Al.sub.2 O.sub.3.2SiO.sub.2) as the predominant crystal phase, and which can be formed spontaneously from a molten glass batch.

REFERENCES:
patent: 2920971 (1960-01-01), Stookey
patent: 3236662 (1966-02-01), MacDowell
patent: 3804608 (1974-04-01), Gaskell et al.

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