Spirotetrathiocarbamates and spirooxothiocarbamates

Details Spirotetrathiocarbamates and spirooxothiocarbamates Spirotetrathiocarbamates and spirooxothiocarbamates

2003-12-19

2010-06-08

Cain, Edward J (Department: 1796)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Processes of preparing a desired or intentional composition...

C549S029000, C549S030000, C549S031000, C549S032000, C549S035000, C549S331000, C549S333000, C549S334000

Reexamination Certificate

active

07732507

ABSTRACT:
Spirotetrathiocarbamates (STOCs) or oxa substituted compounds (SOTOCs) of Formula I: Formula (I) or bisSTOC or bisSOTOC compounds of Formula II: Formula (II) wherein X1, X2, X3, X4, X5, X6, X7, and X8, are independently O or S; and preferably at least two and up to all four of X1, X2, X3and X4, and at least two and up to all four of X5, X6, X7, and X8are sulfur; Z is —CmR22mwherein m=1 to 4; —C(R2)2SC(R2)2—, C(R2)2SSC(R2)2—, or —C(R2)OC(R2)2; n is from 0 to 4; M is selected from CH2Cl, CH2SC(O)R1, CH2SC(S)R1, CH2S(CH2CH2S)qH wherein q is 0, 1 or 2; —CR2═CH2, —CH2OC(O)CR2═CH2, CH2N═C═S, CH2N═C═O, CH2NR2H, CH2OH, CH2SCH2CH2CR2═CH2, phenyl, C(R2)phenyl, furan, thiophene, halogen, C3-C6cycloalkyl, C3-C6heretocyclics, thiol, H, (III) or (IV) wherein A is S, O or phenyl; x is 0 or 1; R1is C1-C22alkyl; and R2is H or C1-C22alkyl have excellent optical properties. Methods for preparing these compositions and optical lenses prepared from the compounds are also provided.

REFERENCES:
patent: 3525752 (1970-08-01), D'Amico et al.
patent: 3652256 (1972-03-01), D'Amico
patent: 3787370 (1974-01-01), Shima et al.
patent: 4810812 (1989-03-01), Matsuda et al.
patent: 5021541 (1991-06-01), Masumoto et al.
patent: 5403938 (1995-04-01), Ohkubo et al.
patent: 6794471 (2004-09-01), Ohkuma et al.
patent: 1193264 (2001-09-01), None
patent: 05105684 (1993-04-01), None
patent: WO 02/57339 (2002-01-01), None
patent: WO 02/051911 (2002-07-01), None
Barbero et al., “Convenient procedure for converting 1,3-dithiolane-2-thiones into 1,3-dithiolan-2-ones,” J. Chem Soc, Perkin Trans 1, pp. 289-294.
Coffen, “Transesterification of Orthothiocarbonates (1),” J. Heterocycl. Chem., 1970, 7, 201.
Moszner et al, “Polymerization of cyclic monomers, 1 Radical polymerization of unsaturated spiro orthocarbonates,” Macromol. Rapid Commun. 16, 667-672 (1995).
Oremus et al., “145. 1,3-Oxathiolan-Synthese: Spirocyclische, 1,3-Oxathiolane aus derLewis-Säure-katalysierten Umsetzung von cyclischen trithiocarbonaten and Oxiranen,” Helvetica Chimica Acta, vol. 74 (1991).
Tagoshi and Endo, “Syntheses of Polyurethanes Containing a Spiroorthocarbonate Moiety in the Main Chain,” Macromolecules 1989, 22, 3834-3838.
Takata and Endo, “A New Class of Polymerizable Sulfur Heterocycles. Cationic Ring-Opening Polymerization of Spiro Tetrathioorthocarbonate,” Macromolecules 1988, 21, 2314.
Takata et al., “Cationic Ring-Opening Polymerizations of Five-Membered Spiro Orthocarbonates: Unsubstituted and 2,8-Diary1-1,4,6,9-tetraoxaspiro[4.4]nonanes,” Macromolecules 25 (1992).

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