Spirobislactone acrylate polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528 93, 528116, 549344, C08G 6308

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active

052604144

ABSTRACT:
This invention is directed to a thermoplastic polymer that is solid at room temperature and which expands on further polymerization, to form a crosslinked polymer, and to a process for preparing the polymer and the crosslinked polymer. In a preferred embodiment the polymer is prepared by polymerizing 10-90 but preferably 20-80 mole percent of a lower alkyl acrylic monomer containing a spirobislactone moiety, 10-90 but preferably 20-80 mole percent of a lower alkyl acrylic monomer containing an epoxide moiety, and 0.1-5 but preferably 0.5-1 mole percent of a lower alkyl acrylic monomer containing a functional moiety chosen from primary amino, secondary amino, mercaptan, and hydroxyl groups which can initiate crosslinking with the spirobislactone moiety. The crosslinked polymer is devoid of a spirobislactone carbonyl absorption band and is insoluble in conventional organic solvents.

REFERENCES:
patent: 4064086 (1977-12-01), Cowsar et al.
patent: 4939251 (1990-07-01), Wang
patent: 5057590 (1991-10-01), Sikes et al.
Pariza et al., Synthetic Communications, vol. 13(3), pp. 243-254 (1983)-ored*.
Sikes et al., "Controlled Shrinkage Polymers: Characterization of Epoxy Resins Cured With Spirobislactones", Journal of Polymer Science: Part A: Polymer Chemistry, vol. 28, 2533-2546 (1990).

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