Spent acid purification process

Chemistry of inorganic compounds – Sulfur or compound thereof – Oxygen containing

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423239, 423522, 423531, C01B 2120, C01B 1790, C01B 1794

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050304364

ABSTRACT:
Contaminants in spent nitric-sulfuric nitration acid can be removed by mixing the spent acid with urea and heating to 75.degree.-150.degree. C. Off-gas from the spent acid/urea reaction is passed through a Group IB, VB, VIB or VIII metal containing catalyst to decompose nitrous oxides and the so-treated off-gas is contacted with spent acid, denitrated spent acid, or fresh sulfuric acid, and optionally air (i.e. oxygen), to absorb oxides of nitrogen. The spent acid scrubbing fluid is then subjected to the same process for removing contaminants.

REFERENCES:
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patent: 4259303 (1981-03-01), Nakaji et al.
patent: 4329155 (1982-05-01), Schlegel
Olsen, Unit Processes and Principles of Chemical Engineering, D. Van Nostrand Co., Inc., 1932 pp. 1-3.
Skoog et al., Fundamentals of Analytical Chemistry, Holt Rinehart and Winston, 1963, p. 189.
Kim et al., Document SPSTL 779 Khp-D82.
Gaedke D. et al., Chem. Tech. (Leipzig) 35(4), pp. 203-205 (1983).
Mistrorico, Braz. Pedido. PI BR 79/7415, Jul. 22, 1980.

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