Spectroscopic method and apparatus

Measuring and testing – Gas analysis – By vibration

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73 6149, 73 6179, 25033913, 356 51, 356436, 356437, G01N 2117

Patent

active

059132345

ABSTRACT:
A method and apparatus for determining the concentration of a substance of interest by gas-coupled photoacoustic spectroscopy (GC-PAS) with an essentially monochromatic beam of radiation in an optical portion of the electromagnetic spectrum; the radiation is selected so as to be absorbed by the substance of interest and the beam is modulated at a sonic frequency which is sufficiently high for generating a primary signal that depends upon the absorption coefficient of the substance of interest as well as upon parameters of operating the method; in order to compensate for these operating parameters, the beam is additionally modulated at a sonic frequency which is sufficiently low for generating a secondary signal which does not depend upon the absorption coefficient of the substance of interest, but, depends only upon parameters of operating the method; a ratio of the first and the second signal is obtained to generate a compensated signal for determining the concentration of the substance of interest.

REFERENCES:
patent: 3948345 (1976-04-01), Rosencwaig
patent: 4028932 (1977-06-01), Rosencwaig
patent: 4436428 (1984-03-01), Watanabe et al.
patent: 4457162 (1984-07-01), Rush et al.
patent: 4557137 (1985-12-01), Kitamori et al.
patent: 4594004 (1986-06-01), Ishida et al.
patent: 4641973 (1987-02-01), Nestler et al.
patent: 4738536 (1988-04-01), Kitamori et al.
patent: 5408327 (1995-04-01), Geiler et al.

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