Spandex fiber with copolymer soft segment

Plastic and nonmetallic article shaping or treating: processes – Forming continuous or indefinite length work – Shaping by extrusion

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2642108, 26421114, 525410, 528 61, 528 64, 528 68, 428364, 428394, D01F 678, C08G 1812, C08G 1848, C08G 1876

Patent

active

050008994

ABSTRACT:
A elastic fibers are formed from spandex polymer that is prepared by reacting a glycol prepared from a tetrahydrofuran/3-methyltetrahydrofuran copolymer with a diisocyanate and then chain extending the thusly capped glycol with a particular mixture of diamines. The fibers have a highly desirable combination of power, hot-wet creep and heat-set efficiency and can be prepared at high spinning and windup speeds.

REFERENCES:
patent: Re29623 (1978-05-01), Oertel
patent: 2929804 (1960-03-01), Steuber
patent: 3180854 (1965-04-01), Schneider
patent: 3428711 (1969-02-01), Hunt
patent: 3642703 (1972-02-01), Suzuki
patent: 4296174 (1981-08-01), Hanzel
patent: 4590285 (1986-05-01), Ernst
patent: 4590312 (1986-05-01), Ernst
patent: 4772677 (1988-09-01), Kausch
patent: 4798880 (1989-01-01), Lodoen
"Polyurethanes from Copolymers of Tetrahydrofuran", Product Licensing Index, Research Disclosures, 8810 (Aug. 1971).
Chiang & Rhodes, "Polymerizability of 3-Methyltetrahydrofuran", Polymer Letters, V. 7, pp. 643-649 (1969).

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