Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
2002-03-27
2004-09-07
Harlan, Rober D. (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C156S334000, C428S095000, C428S096000
Reexamination Certificate
active
06787593
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to sound-deadening composites of metallocene copolymers for use in vehicle applications. More specifically, sound-deadening sheets or carpet backings are provided for use in vehicles.
BACKGROUND OF THE INVENTION
Sound-deadening composites of filled thermoplastic compositions are well known for use in automotive applications. The thermoplastic compositions typically comprise a polymer, plasticizer and filler. A number of patents have been granted for such highly filled thermoplastic compositions as represented by U.S. Pat. Nos. 4,191,798; 4,222,924; 4,263,196; 4,379,190; 4,403,007; 4,430,468; 4,434,258; and 4,438,228. Different systems of polymers, plasticizers and fillers have been proposed. For example, the above-mentioned patents disclose the use of ethylene interpolymers such as ethylene/vinyl ester, ethylene/unsaturated mono- or di-carboxylic acids, or esters of unsaturated acids, etc. Blends of such ethylene interpolymers with other elastomers and polymers have also been proposed.
Notwithstanding the proposal of many different polymer based compositions for use in sound-deadening composites, ethylene vinyl acetate (EVA) has been the most widely used on a commercial basis. However, there is a demand for improved materials which meet a number of balanced properties such as impact strength, tensile, elongation, flex modulus and specific gravity. In addition, where the sound-deadening composition or composite is used in certain applications such as carpet backing, a number of other requirements have been specified by automobile manufacturers. For example, automotive materials or parts must satisfy requirements of resistance to cold, mildew, fogging and flammability.
SUMMARY OF THE INVENTION
This invention is directed to sound-deadening composites for use in vehicles as prepared from compositions containing a metallocene copolymer, plasticizer and filler. These composites have been found to provide a balance of properties heretofore unachieved in commercial automotive applications for sound-deadening composites.
In particular, the metallocene copolymer composites of this invention provide superior low temperature performance, for example, exhibiting flexibility even at temperatures as low as −30° C. without cracking. In addition, improvements in elongation and impact strength far exceeding conventional EVA compositions have been obtained. Other processing problems normally encountered with thermoplastic compositions based on EVA are overcome by these new metallocene copolymer composites.
The sound-deadening composite is based on a metallocene copolymer of ethylene and an &agr;-comonomer having from 4 to 10 carbon atoms, for example, selected from the group consisting of butene, hexene and octene, and mixtures thereof. Composites having the desired properties are obtained by blending the metallocene copolymer in an amount of from about 10 to about 30 percent by weight with an oil plasticizer from about 2 to about 7 percent by weight, and filler from about 60 to about 85 percent by weight. This combination of components enables economical manufacture of the far superior sound absorbing composite which meets the demand of balanced properties of impact strength, tensile, elongation, flex modulus and specific gravity. These composite materials also satisfy the requirements of resistance to cold, mildew, fogging and flammability.
DETAILED DESCRIPTION OF THE INVENTION
The highly filled composite compositions of this invention having the desired sound-deadening property consist essentially of a metallocene copolymer, suitable plasticizer and particulate inorganic filler in amounts to achieve the balanced properties. The metallocene copolymer suitable for use is a copolymer of ethylene and an &agr;-comonomer having 4 to 10 carbon atoms, such as butene, hexene and octene, and mixtures thereof. The presently preferred metallocene copolymers have wide specifications such as a melt flow rate of about 1 to 10 g/10 minutes according to ASTM D 1238, and a density less than about 0.9 or, more particularly, from about 0.860 to about 0.9 g/cc. It has been found that, even with such wide spec material, economies are achieved without sacrificing the balance of properties.
While the metallocene copolymers of ethylene and octene have presently been found preferred, other comonomers such as butene or hexene may be employed with ethylene to provide the desired properties. Furthermore, the metallocene copolymers may be blended with other polyolefins such as polyethylene, polypropylene, low density polyethylene (LDPE), linear low density polyethylene (LLDPE), ultra low density polyethylene (ULDPE), and others, in amounts which do not materially affect the essential characteristics or advantages of the present invention.
The term “metallocene copolymer” is well understood to a person of ordinary skill in the art as related to those polymers prepared from metallocene or single site catalysts. The metallocene-catalyzed ethylene-based polymers used in the present invention are preferably wide spec metallocene copolymers. These materials are available from DOW Plastics, or Exxon Chemical Company under the trademarks Engage® or Exact®, respectively. Prime grades of these polymers, for example, include those sold under the names Engage 8500, Exact 3035, Exact 3027, Exact 4150 and Exact 4041. Engage 8500 is a polyolefin elastomer of ethylene-octene copolymer that has a melt index of 4-6 g/10 min under ASTM D1238, and a density of 0.8670-0.8730 g/cc according to ASTM D792. Exxon Exact 3035 and 3027 are ethylene-based butene plastomers each having a density of 0.9 g/cc and a melt flow of 3.5 g/10 min according to Exxon's methods. Exxon Exact 4041 is an ethylene-based butene plastomer having a density of 0.880 g/cc and a melt flow of 3.0 g/10 min according to Exxon's methods. Exxon Exact 4150 plastomer is an ethylene-based hexene plastomer having a density of 0.895 g/cc and a melt flow of 3.5 g/10 min according to Exxon methods. The metallocene process, and particularly the catalysts and catalyst support systems are the subject of patents including U.S. Pat. Nos. 4,542,199; 5,189,192; 5,352,649 and 5,349,100. There is a significant amount of information in the literature concerning these polymers that have been developed and reference may be made to, for example, U.S. Pat. Nos. 4,937,299; 5,272,236; 5,278,272; 5,665,800; and 5,783,638. All of these patents that relate to metallocene copolymers and the above commercial information available with respect to the available products are incorporated herein by reference.
The highly filled composite is made from an extrusion recipe of a composition which consists essentially of from about 10 to about 30 percent by weight of the metallocene copolymer with from about 2 to about 7 percent by weight plasticizer and from about 60 to about 85 percent by weight of inorganic particulate filler. The terms “consisting essentially of” mean that the named ingredients are essential, but other ingredients may be used providing they do not alter the material characteristics of the composite. Within these ranges of components, the desirable benefits of impact strength, tensile, elongation, flex modulus and specific gravity are obtained. Furthermore, the superior resistance to low temperatures has been achieved.
In a preferred mode according to the principles of this invention, a metallocene copolymer of ethylene and octene has been employed with wide spec properties of melt flow rate of about 1 to about 10 g/10 minutes according to ASTM D 1238 and a density of from about 0.860 to about 0.9 g/cc. More specifically, in the preferred mode, when amounts of this metallocene copolymer of ethylene and octene of about 18 to about 22 percent by weight are combined with essentially a paraffinic oil plasticizer of from about 3 to about 5 percent by weight and a calcium carbonate filler of from about 78 to about 82 percent by weight, superior performance properties have been achieved.
The plasticizer employed in the composition is prefe
Bell Steven E.
Hull Dwight D.
Rice Jeffrey L.
Young Dennis C.
Harlan Rober D.
Josephic David J.
Lear Corporation
Panagos Bill C.
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