Solventless process for producing dialkyl fumarate-vinyl acetate

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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5263295, 526330, 252 56D, 252 56R, C08F22210, C08F22012, C08F21802

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active

047726741

ABSTRACT:
Process for the bulk polymerization of vinyl acetate with a diester are disclosed which are carried out in the absence of a solvent and including reacting the vinyl acetate and fumaric acid diester with a peroxide catalyst at specified molar ratios and up to reaction temperatures of from 255.degree. to 320.degree. F. to produce fumarate vinyl acetate copolymers having number average molecular weight below 50,000 for use as lubricating oil and fuel oil additives.

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