Solvent system for polysaccharides

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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106187, 106203, 252364, 536 84, 536 99, 106197R, C08B 1102, C08B 1600

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active

040976661

ABSTRACT:
Natural or modified polysaccharides are dissolved in a solvent system comprising dimethyl sulfoxide and formaldehyde. The solvent system is particularly suitable for dissolving cellulose due to the fact that cellulose is rapidly dissolved under moderate conditions of temperature and pressure. The dissolved polysaccharides are readily recovered from the solvent system by diluting the solvent system with water or a short chain alcohol.

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Crown Zellerbach, Patents on uses of Dimethyl Sulfoxide (DMSO), 7/1963, pp. 1-31.
Bollettino Chimico Farmaceutico Abstract, vol. 102/1963, Dimethylsulfoxide, An Aquo-Mimetic Solvent, pp. 1-31.
"The New Cellulose Solvent: Dimethyl Sulfoxide-Paraformaldehyde", Johnson et al., 39th Executive Converence, The Institute of Paper Chemistry, Appleton, Wis. May 8, 1975.
"Dimethyl Sulfoxide-Paraformaldehyde: A Nondegrading Solvent for Cellulose", Johnson et al., Technical Paper Series No. 5, Apr. 1975, (first presented at the eighth Cellulose Conference at Syracuse, New York, May 19-23, 1975).

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