Solvent extraction of synfuel liquids

Mineral oils: processes and products – Refining – Nitrogen contaminant removal

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208 8LE, 208 11LE, 208 57, 208 78, 208143, 208 87, 208 88, 208 96, 208210, 208211, 208236, 208240, 208289, 208291, 208311, 208318, 208326, 208335, C10G 4502, C10G 6704

Patent

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042972060

ABSTRACT:
An improvement in the solvent extraction of nonhydrocarbons from a synfuel liquid, e.g., shale oil, involves that the extract from the extractor, rather than being recycled directly back to the extractor, is first hydrotreated. A further improvement involves that a portion of the hydrotreated extract is fractionated and a light fraction is returned to the extractor. Use of the hydrotreated extract as recycle increases the efficiency of the extractor. A still further improvement involves the use as a selective solvent of one of the following: dialkylformamide, aldehydomorpholine, keto-morpholine, morpholine or an aliphatic aromatic ketone. These preferred solvents have the advantage of providing a clear interface between the extract and raffinate in the extractor. Removal of the nonhydrocarbons permits production of more hydrocarbons having enhanced utility as a jet fuel from a synfuel liquid than otherwise would be possible.

REFERENCES:
patent: 2026812 (1936-01-01), Birkhimer
patent: 2067137 (1937-01-01), Clarke
patent: 2279550 (1942-04-01), Benedict et al.
patent: 2287736 (1942-06-01), Hersberger
patent: 2357667 (1944-09-01), Kuhn
patent: 2906693 (1959-09-01), Donaldson
patent: 4159940 (1979-07-01), Smith

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