Solution mining of carbonate/bicarbonate deposits to produce sod

Chemistry: physical processes – Physical processes – Crystallization

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4232062, 423421, 299 5, C01D 724, F21C 4116

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active

057662703

ABSTRACT:
A solution mining process for recovering sodium values from an underground deposit of a sodium bicarbonate containing ore is disclosed. The process involves contacting the ore with an aqueous sodium carbonate-containing solution to produce a dilute brine which is stripped with steam to reduce the bicarbonate content and increase the carbonate content. The dilute carbonate/bicarbonate solution from the stripper is fed to a sodium carbonate decahydrate crystallizer to produce pure sodium carbonate decahydrate crystals and a mother liquor containing less than about 4% sodium bicarbonate.

REFERENCES:
patent: 1396841 (1921-11-01), Hirschkind
patent: 1853275 (1932-04-01), Houghton et al.
patent: 1911794 (1933-05-01), Britton
patent: 2049249 (1936-07-01), Cunningham
patent: 2133455 (1938-10-01), Keene et al.
patent: 2193817 (1940-03-01), Houghton
patent: 2388009 (1945-10-01), Pike
patent: 2625384 (1953-01-01), Pike et al.
patent: 2639217 (1953-05-01), Pike
patent: 2770524 (1956-11-01), Seaton et al.
patent: 2780520 (1957-02-01), Pike
patent: 2957822 (1960-10-01), Frint
patent: 2962348 (1960-11-01), Seglin et al.
patent: 2970037 (1961-01-01), Caldwell et al.
patent: 2989369 (1961-06-01), Osborne
patent: 3028215 (1962-04-01), Frint
patent: 3037849 (1962-06-01), Frint et al.
patent: 3050290 (1962-08-01), Caldwell et al.
patent: 3072466 (1963-01-01), Bauer et al.
patent: 3084026 (1963-04-01), Frint et al.
patent: 3097830 (1963-07-01), Love et al.
patent: 3111306 (1963-11-01), Love et al.
patent: 3113834 (1963-12-01), Beecher et al.
patent: 3119655 (1964-01-01), Frint et al.
patent: 3184287 (1965-05-01), Gancy
patent: 3212848 (1965-10-01), Tasiaux
patent: 3246962 (1966-04-01), Miller
patent: 3264057 (1966-08-01), Miller
patent: 3309171 (1967-03-01), Gancy
patent: 3328130 (1967-06-01), Gancy
patent: 3368866 (1968-02-01), Seguela
patent: 3425795 (1969-02-01), Howard et al.
patent: 3451767 (1969-06-01), Saeman
patent: 3455647 (1969-07-01), Gloster
patent: 3459497 (1969-08-01), Coglaiti, Jr. et al.
patent: 3498744 (1970-03-01), Frint et al.
patent: 3525434 (1970-08-01), Garrett et al.
patent: 3528766 (1970-09-01), Coglaiti, Jr. et al.
patent: 3655331 (1972-04-01), Seglin et al.
patent: 3656892 (1972-04-01), Bourne et al.
patent: 3667902 (1972-06-01), Blumenthal
patent: 3695831 (1972-10-01), Goldstein
patent: 3717698 (1973-02-01), Ilardi et al.
patent: 3725014 (1973-04-01), Poncha et al.
patent: 3792902 (1974-02-01), Towell et al
patent: 3819805 (1974-06-01), Graves et al.
patent: 3836628 (1974-09-01), Ilardi et al.
patent: 3838189 (1974-09-01), Sopchak et al.
patent: 3869538 (1975-03-01), Sproul et al.
patent: 3870780 (1975-03-01), Guptill
patent: 3904733 (1975-09-01), Gancy et al.
patent: 3927175 (1975-12-01), Garofano et al.
patent: 3933977 (1976-01-01), Ilardi et al.
patent: 3953073 (1976-04-01), Kube
patent: 3956457 (1976-05-01), Port et al.
patent: 3966541 (1976-06-01), Sadan
patent: 3975499 (1976-08-01), Walden
patent: 3981686 (1976-09-01), Lobunez et al.
patent: 3984527 (1976-10-01), Gancy et al.
patent: 3991160 (1976-11-01), Gancy et al.
patent: 4019872 (1977-04-01), Walden
patent: 4021525 (1977-05-01), Poncha
patent: 4021526 (1977-05-01), Gancy et al.
patent: 4021527 (1977-05-01), Baadsgaard
patent: 4022867 (1977-05-01), Gancy et al.
patent: 4022868 (1977-05-01), Poncha
patent: 4032616 (1977-06-01), Artur et al.
patent: 4039617 (1977-08-01), Kuo
patent: 4039618 (1977-08-01), Gancy et al.
patent: 4044097 (1977-08-01), Gancy et al.
patent: 4083939 (1978-04-01), Lobunez et al.
patent: 4104033 (1978-08-01), Mahn et al.
patent: 4148684 (1979-04-01), Farin
patent: 4151261 (1979-04-01), Poncha et al.
patent: 4158043 (1979-06-01), Gloster
patent: 4160812 (1979-07-01), Conroy et al.
patent: 4169812 (1979-10-01), Smith et al.
patent: 4183901 (1980-01-01), Ilardi et al.
patent: 4202667 (1980-05-01), Conroy et al.
patent: 4252781 (1981-02-01), Fujita et al.
patent: 4260594 (1981-04-01), Verlaeten et al.
patent: 4286967 (1981-09-01), Booth, Jr. et al.
patent: 4288419 (1981-09-01), Copenhafer et l.
patent: 4291002 (1981-09-01), Arnold et al.
patent: 4299799 (1981-11-01), Ilardi et al.
patent: 4344650 (1982-08-01), Pinsky et al.
patent: 4374102 (1983-02-01), Connelly et al.
patent: 4401635 (1983-08-01), Frint
patent: 4472280 (1984-09-01), Keeney
patent: 4498706 (1985-02-01), Ilardi et al.
patent: 4519806 (1985-05-01), Copenhafer et al.
patent: 4557910 (1985-12-01), Meadow
patent: 4564508 (1986-01-01), Fairweather et al.
patent: 4584077 (1986-04-01), Chlanda et al.
patent: 4652054 (1987-03-01), Copenhafer et al.
patent: 4738836 (1988-04-01), Poncha et al.
patent: 4743439 (1988-05-01), Ready
patent: 4781899 (1988-11-01), Rauh et al.
patent: 4814151 (1989-03-01), Benke
patent: 4815790 (1989-03-01), Rosar et al.
patent: 4869882 (1989-09-01), Dome et al.
patent: 5043149 (1991-08-01), Frint et al.
patent: 5192164 (1993-03-01), Frint et al.
patent: 5238664 (1993-08-01), Frint et al.
patent: 5270023 (1993-12-01), May et al.
patent: 5283054 (1994-02-01), Copenhafer et al.
patent: 5290322 (1994-03-01), Breton et al.
patent: 5308455 (1994-05-01), Bourgeois
patent: 5362688 (1994-11-01), Porta et al.
patent: 5395497 (1995-03-01), Bourgeois
patent: 5396863 (1995-03-01), Ninane et al.
patent: 5609838 (1997-03-01), Neuman et al.
Butler, J.N., Carbon Dioxide Equilibria and Their Application, Lewis Publishers, Chelsea, MI, pp. 30-39, 221, 1991.
Defensive Publication, United States Patent Office, "Process For Producing Crystalline Anhydrous Sodium Carbonate", T928,002, 1 page, Nov. 5, 1974.
Eickmeyer, A.G., "Carbon Dioxide Removal, IV, Catacarb", Fertiizer Science Technology Series, 2, pp. 165-169, 1974.
ZA 87-9599 871222 ZAX South African Patent (Abstract Only: Chemical Abstract No. 110:176149).
Garrett, D., "Solution Mining", Natural Soda Ash, Von Nostrand Reinhold, New York, NY, 1992, pp. 336-355.
Harned et al., "The Thermodynamics of Ionized Water in Sodium Chloride Solutions", vol. 57, pp. 1873-1876, Oct. 1935.
Mahajani et al., "The Stripping of CO.sub.2 From Amine-Promoted Potash Solutions at 100.degree. C.", Chemical Engineering Science, vol. 38, No. 2, pp. 321-327, 1983.
Nii et al., "Regeneration of CO.sub.2 -Loaded Carbonate Solution By Reducing Pressure", Journal of Chemical Engineering of Japan, vol. 28, No. 2, pp. 148-153, 1995.
Peiper et al., "Thermodynamics of Aqueous Carbonate Solutions Including Mixtures of Sodium Carbonate, Bicarbonate and Chloride", J. Chem. Thermodynamics, 14, pp. 618-638, 1982.
Pohorecki et al., "Desorption with chemical reaction in the system CO.sub.2 -aqueous solution of potassium carbonate", The Chemical Engineering Journal, 46, pp. 1-7, 1991.
Rao, D. Phaneswara, "Design of packed towers for absorption and desorption of carbon dioxide using hot promoted K.sub.2 CO.sub.3 solution", Gas Separation & Purification, vol. 5, pp. 177-180, Sep. 1991.
Sarbar et al., "The activity and osmotic coefficients of aqueous sodium bicarbonate solutions", Chem. Thermodynamics, 14, pp. 967-976, 1982.
Savage et al., "Chemical Absorption and Desorption of Carbon Dioxide From Hot Carbonate Solutions", Chemical Engineering Science, vol. 35, pp. 1513-1522, 1980.
Taylor, E., "Thermodynamics of Sodium Carbonate in Solution", Institute of Paper Chemistry, pp. 653-657, Jul. 1955.
Vanderzee, Cecil, "Thermodynamic properties of solutions of a hydrolyzing electrolyte: relative partial molar enthalpies and heat capacities, solvent activities, osmotic coefficients, and solute activity coefficients of aqueous sodium carbonate", J. Chem. Thermodynamics, 14, pp. 1051-1067,1982.
Yakovlev et al., "Constant of the Second Stage of Dissociation of Carbonic Acid in Concentrated Na.sub.2 SO.sub.4 Solutions", Zh. Prikl. Khim (Leningrad), vol. 62, No. 6, No. 6, pp. 1276-1277, 1989.

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