Soluble polyimide resin comprising polyalicyclic structure

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528125, 528128, 528171, 528172, 528173, 528174, 528175, 528179, 528183, 528185, 528188, 528220, 528229, 528350, 528351, C08G 7310, C08G 6926

Patent

active

060545542

ABSTRACT:
The invention herein relates to a novel soluble polyimide resin comprising polyalicyclic structures and the process of preparation of the same, wherein aromatic tetracarboxylic dianhydride and novel aromatic diamine having an polyalicyclic group with various structures are used to yield a novel form of a polyimide resin, which has superior heat-resistance, solubility, and transparency.
More specifically, the invention herein relates to a novel polyimide resin having excellent heat-resistance and solubility, which is prepared by means of reacting diamine monomers having a novel chemical structure with various types of aromatic carboxilic dianhydrides, in stead of aromatic diamine used for the preparation of the conventional polyimide resin. As a result, the polymers so obtained had the glass transition temperature of 260.degree. C..about.410.degree. C. and showed a increase in solubility in proportion to the increase in a number of the aromatic rings between two phenyl groups. Further, the polymers herein showed superior solubility at room temperature in various types of organic solvents, e.g., m-cresol, N-methylpyrrolidone or dimethylacetamide.

REFERENCES:
patent: 5466732 (1995-11-01), Tomioka et al.
patent: 5554684 (1996-09-01), Choi et al.
patent: 5604041 (1997-02-01), Choi

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