Solubilization of low 2-phenyl alkylbenzene sulfonates

Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

510421, 510424, 510426, 510427, 510432, C11D 1700, C11D 1708

Patent

active

060838973

ABSTRACT:
Methods and compositions relating to solubilization of alkylbenzene sulfonate surfactants in detergent formulations. Addition of one or more polyethylene glycols to detergents including low 2-phenyl linear alkylbenzene sulfonate surfactants may be used to increase solubility of the low 2-phenyl linear alkylbenzene sulfonate surfactants. Increased solubility of the low 2-phenyl linear alkylbenzene sulfonate surfactants serves to lower the cloud point of the detergents, permitting formulation of liquid detergent compositions containing greater concentrations of low 2-phenyl linear alkylbenzene sulfonate surfactants.

REFERENCES:
patent: 3349141 (1967-10-01), Sweeney
patent: 3776962 (1973-12-01), Alul et al.
patent: 3951960 (1976-04-01), Heath et al.
patent: 3980713 (1976-09-01), Matsunaga et al.
patent: 3985687 (1976-10-01), Inamorato et al.
patent: 3993659 (1976-11-01), Meyer
patent: 4028283 (1977-06-01), Murata et al.
patent: 4244840 (1981-01-01), Straw
patent: 4301317 (1981-11-01), Young
patent: 4396520 (1983-08-01), Payne et al.
patent: 4618446 (1986-10-01), Haslop et al.
patent: 4645623 (1987-02-01), Dolan et al.
patent: 4663069 (1987-05-01), Lienado
patent: 4668423 (1987-05-01), Drozd et al.
patent: 4687593 (1987-08-01), Dolan et al.
patent: 4692271 (1987-09-01), Messenger et al.
patent: 4746461 (1988-05-01), Zielske
patent: 4753754 (1988-06-01), Messenger et al.
patent: 4760200 (1988-07-01), Keen et al.
patent: 4973780 (1990-11-01), Johnson et al.
patent: 5034564 (1991-07-01), Kocal
patent: 5086193 (1992-02-01), Sy
patent: 5146026 (1992-09-01), Berna Tejero et al.
patent: 5147576 (1992-09-01), Montague et al.
patent: 5152933 (1992-10-01), Holland
patent: 5167872 (1992-12-01), Pancheri et al.
patent: 5196574 (1993-03-01), Kocal
patent: 5242615 (1993-09-01), Urfer et al.
patent: 5256828 (1993-10-01), Cuscurida et al.
patent: 5273644 (1993-12-01), Wegerer
patent: 5344997 (1994-09-01), Kocal
patent: 5415814 (1995-05-01), Ofosu-Asante et al.
patent: 5446223 (1995-08-01), Smith, Jr. et al.
patent: 5550115 (1996-08-01), Garst et al.
patent: 5580848 (1996-12-01), Drapier
patent: 5631205 (1997-05-01), Killick et al.
patent: 5703028 (1997-12-01), Erilli et al.
patent: 5716925 (1998-02-01), Mondin et al.
patent: 5719118 (1998-02-01), Crutcher et al.
patent: 5780417 (1998-07-01), Gorlin
Goddard, "Polymer-surfactant interaction Part I. Uncharged water-solublel polymers and charged surfactants," Colloids and Surfaces, 19:255-300, 1986. NMA.
Gorlin et al., "Liquid automatic dishwasher detergents," In: Liquid Detergents, Kuo-Yann Lai (Ed.), Marcel Dekker, Inc., NY, Chapter 9, pp. 325-380, 1997. NMA.
Huntsman brochure entitled: "Surfactants: A complete line of specialty surfactants and intermediates," 1996. NMA.
Huntsman brochure entitled: "Surfactants: Detergents," 1996. NMA.
Huntsman brochure entitled: "Surfactants: Linear Alkylbenzenes Alkylate 215, 225 & 229," 1996. NMA.
Huntsman brochure entitled: "Surfactants: Product flow chart," 1998. NMA.
Huntsman Technical Bulletin, ALKYLATE 215, 1997. NMA.
Huntsman Technical Bulletin, ALKYLATE 225, 1997. NMA.
Huntsman Technical Bulletin, ALKYLATE 229, 1997. NMA.
Huntsman Surfactant Application Notes, vol. 2, POGOL .TM.Polyethylene Glycols, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L42, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L44, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L61, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L62, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L62LF, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L64, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L81, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-L101, 1997. NMA.
Huntsman Technical Bulletin, Surfonic.RTM.POA-25R2, 1997. NMA.
Huntsman Technical Bulletin, POGOL.TM. 200 Polyethylene Glycol, 1997. NMA.
Brown et al., "Poly(ethylene oxide)-sodium dodecyl sulfate interactions studied using static and dynamic light scattering," Macromolecules, 25:7192-7198, 1992. NMA.
Cohen et al., "Influence of 2-phenyl alkane and tetralin content on solubility and viscosity of linear alkylbenzene sulfonate," JAOCS, 72(1):115-122, 1995. NMA.
Contractor et al., "Interaction of PEO-PS-PEO block copolymers with ionic surfactants in aqueous solution," Pure Appl. Chem., A34(12):2497-2507, 1997.
Cox and Smith, "Effect of LAB composition on LAS performance," INFORM, 8(1):19-24, 1997. NMA.
de Ameida et al., "Linear alkylbenzene," JAOCS, 71(7):675-693, 1994. NMA.
Drozd, "An introduction to light duty (dishwashing) liquids Part I. Raw materials," Chemical Times & Trends, pp. 29-57, 1984. NMA.
Drozd and Gorman, "Formulating characteristics of high and low 2-phenyl linear alkylbenzene sulfonates in liquid detergents," JAOCS, 65(3):398-404, 1988. NMA.
"Formulating Characteristics of High and Low 2-Phenyl Linear Alkylbenzene Sulfonates in Liquid Detergents," Presented at 77th Annual AOCS Meeting, May 17, 1986, Honolulu, HI by Stepan Company, Northfield, IL.
Friberg and Chiu, "Hydrotropes," J. Dispersion Sci. Technol., 9(5&6):443-457, 1988-89.
Witco brochure entitled "Fabric Care: Surfactant & Specialty Products," 1996. NMA.
Co-pending U.S. application No. 09/303,096 dated Apr. 29, 1999. NMA.
Blease et al., In: Defoaming Theory and Industrial Applications, P.R. Garrett (Ed.), Ch. 8, pp. 299-323, 1993.
Co-Pending U.S. application No. 60/115,408 filed Jan. 11, 1999 (HNTC:064PZ1).
Co-Pending U.S. application No. 60/139,441 filed Jun. 15, 1999 (HNTC:064PZ2).
Co-Pending U.S. Provisional Patent Application Entitled "Concentrated Surfactant Blends," filed Jun. 30, 1999 (HNTC:066PZ1).
"Surfactants Literature," 1999. NMA.
Akzo Nobel catalog entitled "Surface Chemistry: Industrial surfactants general catalog, nitrogen derivatives."NMA.
Friberg, "Microemulsions and micellar solutions," Microemulsions Theory and Practice, p. 133-134. NMA.
Huntsman brochure entitled "Surfactants: SURFONIC.RTM. Alcohol Ethoxylates," 1996. NMA.
Huntsman brochure entitled "Surfactants: SURFONIC.RTM. Alkylphenol Ethoxylates," 1996. NMA.
Huntsman Technical Bulletin, SURFONIC.RTM. PEA-25, 1999. NMA.
Huntsman Technical Bulletin, SURFONIC.RTM. T-15, 1999. NMA.
Kirk-Othmer ed. "Microemulsions," Ency. of Chem. Tech., Supplement vol., pp. 299-303. NMA.
Kirk-Othmer ed. "Surfactants," Ency. of Chem. Tech., 23:478-491. NMA.
Pillai and Shah, eds., Dynamic Properties of Interfaces and Association Structures, pp. 55, 127, 142, 156, 178, 179, 183, 194, 196, 233, 264.
Prince, "Schulman's microemulsions," Microemulsions Theory and Practice, p. 1-4, 8-9, 17-18, 113-114, 116. NMA.
Rosano and Clausse, eds., Microemulsion Systems, p. 280. NMA.
Stepan brochure entitled "Your complete surfactant source." NMA.
Tomah Products, Inc. brochure entitled "The Chemistry of Tomah Products, Inc." NMA.
Moreno et al., "Influence of structure and counterions on physicochemical properties of linear alkylbenzene sulfonates," JAOCS, 67(8):547-552, 1990. NMA.
Nace (Ed.), In: Nonionic Surfactants: Polyoxyalkylene Block Copolymers, vol. 60, Marcel Dekker, Inc., NY, 1996. NMA.
Pluronic & Tetronic Block Copolymer Surfactants, BASF Catalogue, pp 1-29, 1989. NMA.
Sachdev and Krishnan, "Heavy-duty liquid detergents," In: Liquid Detergents, Kuo-Yann Lai (Ed.), Marcel Dekker, Inc., NY, Chapter 8, pp. 261-324, 1997. NMA.
Smith, "Impact of composition on the performance of sodium linear alkylbenzenesulfonate (NaLAS)," JAOCS, 74(7):837-845, 1997.
Sweeney and Olson, "Performance of straigh-chain alkylbenzene sulfonates (LAS) in heavy-duty detergents," 41:815-822, 1964. NMA.
Tjepkema et al., "Relationship between the structure of phenyldodecane isomers and their performance as detergent base materials," Fifth World Petroleum Congress, Section IV-Paper 21, pp 237-243, 1959. NMA.
van Os et al., "Alkylarenesulphonates: The effect of chemical structure on physico-chemical properties," Tenside Surf. Det., 29(3):175-189, 1992. NMA.
Co-pending U.S. application No. 09/141,660 filed Aug. 28, 1998 (HNTC:060).
Co-pending U.S. application No. 08/598,692 filed Feb. 8, 1996 (HNSC:002).
Huntsman Technical

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Solubilization of low 2-phenyl alkylbenzene sulfonates does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Solubilization of low 2-phenyl alkylbenzene sulfonates, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Solubilization of low 2-phenyl alkylbenzene sulfonates will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1486516

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.