Radiant energy – Photocells; circuits and apparatus – Photocell controlled circuit
Reexamination Certificate
2000-06-02
2001-09-18
Lee, John R. (Department: 2878)
Radiant energy
Photocells; circuits and apparatus
Photocell controlled circuit
C250S214100, C250S216000, C438S069000
Reexamination Certificate
active
06291811
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to a solid state image sensing device and, more particularly, to a solid state image sensing element, a process of fabrication thereof and a solid state image sensing device equipped with the solid state image sensing element.
DESCRIPTION OF THE RELATED ART
A CCD (Charge Coupled Device) type image sensing device is a typical example of the solid state image sensing device, and is described hereinbelow. However, the following description is applicable to another kind of solid state image sensing device such as a MOS (Metal-Oxide-Semiconductor) type solid state image sensing device.
FIG. 1
 illustrates the first prior art slid state image sensing device. A p-type well 
1
 is formed in a surface portion of an n-type silicon substrate 
2
, and an n-type impurity region 
3
 is nested in the p-type well 
1
. A heavily-doped p-type impurity region 
4
 is formed over the n-type impurity region 
3
, and the heavily-doped p-type impurity region 
4
 and the n-type impurity region 
3
 form a p-n junction serving as a photo diode.
An n-type charge transfer region 
5
 is further formed in the p-type well 
1
, and is spaced from the photo diode, i.e., the n-type impurity region 
3
 and the heavily-doped p-type impurity region 
4
. Though not shown in 
FIG. 1
, photo diodes are arranged along the n-type charge transfer region 
5
, and the photo diodes and the n-type charge transfer region 
5
 form in combination an image sensing line. A heavily doped p-type impurity region 
6
 is formed in such a manner as to of the image sensing line, and electrically isolates the photo diodes and the n-type charge transfer region 
5
 from adjacent image sensing lines. Thus, a large number of photo diodes are arrayed in the p-type well 
1
. However, description is focused on only one of the photo diodes and the n-type charge transfer region 
5
.
A read-out transistor 
7
 is associated with the photo diode and the n-type charge transfer region 
5
. In detail, a surface portion of the p-type well 
1
 between the photo diode and the n-type charge transfer region 
5
 provides a channel region 
7
a
, and the channel region 
7
a 
is covered with a gate oxide layer 
7
b
. A charge transfer electrode 
7
c 
is formed on the gate oxide layer 
7
b
, and is covered with a silicon oxide layer 
8
. The silicon oxide layer 
8
 is over-lain by a photo shield layer 
9
, and an opening 
9
a 
is formed in the photo shield layer 
9
 over the photo diode. For this reason, image-carrying light is incident onto the photo diode through the opening 
9
a
, and the n-type charge transfer region 
5
 is prevented from the light.
The photo shield layer 
9
 is covered with a transparent insulating layer 
10
, and the opening 
9
a 
is filled with the transparent material. A thick photo resist layer 
11
 is laminated on the transparent insulating layer 
10
, and provides a flat upper surface 
11
a
. An on-chip lens 
12
 is formed on the flat upper surface 
11
a
, and is located over the photo diode so as to focus the image carrying light on the photo diode. The thick photo resist layer 
11
 is made from photo resist solution through a baking. The on-chip lens 
12
 is also made from a piece of photo resist. A photo resist layer is patterned into pieces of photo resist through lithographic techniques, and the piece of photo resist thermally cured at 150 degrees to 200 degrees in centigrade. Then, the piece of photo resist is shaped into a semi-spherical configuration as shown.
The second prior art solid state image sensing device is disclosed in Japanese Patent Publication of Unexamined Application (JPA) No. 2-65171, and 
FIG. 2
 illustrates the second prior art solid state image sensing device. A p-type well 
21
 is formed in a surface portion of an n-type silicon substrate 
22
, and an n-type impurity region 
23
 is nested in the p-type well 
21
. A heavily-doped p-type impurity region 
24
 is formed over the n-type impurity region 
23
, and the heavily-doped p-type impurity region 
24
 and the n type impurity region 
23
 form a p-n junction serving as a photo diode.
An n-type charge transfer region 
25
 is further formed in the p-type well 
21
, and is spaced from the photo diode. The photo diode and the n-type charge transfer region 
25
 form an image sensing line together with other photo diodes. A heavily doped p-type impurity region 
26
 is formed in such a manner as to surround the image sensing line, and electrically isolates the photo diodes and the n-type charge transfer region 
25
 from adjacent image sensing lines.
A read-out transistor 
27
 is associated with the photo diode and the n-type charge transfer region 
25
, and comprises a channel region 
27
a
, a gate oxide layer 
27
b 
over the channel region 
27
a 
and a charge transfer electrode 
27
c 
formed on the gate oxide layer 
27
b
. The charge transfer electrode 
279
 is covered with a silicon oxide layer 
28
, and the silicon oxide layer 
28
 is overlain by a photo shield layer 
29
. An opening 
29
a 
is formed in the photo shield layer 
29
 over the photo diode, and allows image-carrying light to be incident onto the photo diode through the opening 
29
a
. The photo shield layer 
29
 prevents the n-type charge transfer region 
25
 from the incident light. The photo shield layer 
29
 is topographically covered with a transparent insulating layer 
30
, and the transparent insulating layer 
30
 forms a deep recess 
30
a
. The deep recess 
30
a 
is located over the photo diode. The deep recess 
30
a 
is partially filled with silica glass, and the piece of silica glass 
31
 forms a curved upper surface 
32
. The curved upper surface 
32
 forms a shallow recess nested in the deep recess 
30
a
. The shallow recess is filled with silicon nitride, and the silicon nitride has a refractive index larger than the silica glass. For this reason, the piece of silicon nitride 
33
 serves as a lens. The upper surface of the lens 
33
 is planarized as shown.
The on-chip lens 
12
 occupies the wide area over the photo diode 
3
/
4
 and the n-type charge transfer region 
5
, and gathers the incident light fallen thereonto. For this reason, the photo diode 
3
/
4
 is sensitive to the variation of the incident light. However, the first prior art solid state image sensing device encounters a problem inhigh price. As described hereinbefore, the on-ship lens 
12
 is formed of photo resist solidified through the baking, and, accordingly, is brittle. The brittle on-chip lens is liable to be broken during the fabrication of the first prior art solid state image sensing device, and decreases the production yield. This makes the price of the first prior art solid state image sensing device high.
Another reason for the high price is serious influences of dust. The on-chip lenses 
12
 project from the flat upper surface 
11
a 
of the photo resists layer 
11
, and form valleys therebetween. If a dust particle falls into the valley, the dust particle is hardly eliminated from the valley, and makes the product defective. For this reason, the first prior art solid state image sensing device requires extremely high cleanliness, and such an extremely high clean ambience increases the production cost of the first prior art solid state image sensing device.
Yet another reason for the high price is a complicated packaging structure. The on-chip lens 
12
 has the exposed curved surface. If the exposed curved surface is held in contact with transparent layer which has a large refractive index, the on-ship lens 
12
 loses the convergent function. For this reason, the on-chip lens 
12
 is required to be exposed to the air, or is covered with an extremely low refractive index material layer. The manufacturer takes these requirements into account, and designs the package for the first prior art solid state image sensing device. The package is complicated, and increases the production cost.
The second prior art solid state image sensing device is less costly, because the curved surface of the lens 
33
 is embedded into the piece of silica glass 
31
. However, the second pr
Lee John R.
NEC Corporation
Sughrue Mion Zinn Macpeak & Seas, PLLC
LandOfFree
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