Solid state cell wherein an anode, solid electrolyte and cathode

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

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429193, 429218, 429224, H01M 618

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active

045073716

ABSTRACT:
The invention provides an electrochemical cell wherein an anode, solid electrolyte and cathode each comprise a cubic-close-packed framework structure having, as its basic structural unit, a unit of the formula (B.sub.2)X.sub.4.sup.n- which is the structural unit of an A(B.sub.2)X.sub.4 spinel. The structure accommodates active cations M.sup.+ capable of diffusion therethrough. The invention also extends to electrodes and electrolytes of the above type for use in such cells.

REFERENCES:
patent: 4136233 (1979-01-01), Eisenberg
patent: 4176170 (1979-11-01), Kasper et al.
patent: 4246253 (1981-01-01), Hunter
patent: 4366215 (1982-12-01), Coetzer et al.
"Preliminary Investigation of the Electrochemical Performance of Alpha-Fe.sub.2 O.sub.3 and Fe.sub.3 O.sub.4 Cathodes in High Temperature Cells", Coetzer, et al., Materials Research Bulletin, vol. 16, pp. 591-596, (1981).
"Transition Metal Sulfide-Lithium Organic Electrolyte Rechargeable Cells"-Eisenberg-Proceedings of the 28th Power Sources Symposium, pp. 155-157, (1978).
"Electrode Reactions and Iron Oxide Selections for the Thermal Cell Mg/LiCl-KCl/FeO.sub.x Ni", Selis, et al., Journal of the Electrochemical Society, Jun. 1963, pp. 469-476.
Japanese published patent specifications 78/104085, 78/120629, 78/125326, Sanyo Electric Company.
"Evaluation of Lithium Titanates as Cathode Materials", Liebert, PhD., Thesis, Stanford University, 1977, Abstract & pp. 95, 100 and 117-119.
"Preparation of New Crytal Form of Manganese Dioxide: Lamda-MnO.sub.2 ", Hunter, Journal of Solid State Chemistry 39, pp. 142-147, (1981).

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