Solid solution catalyst containing iron cations for the oxychlor

Details Solid solution catalyst containing iron cations for the oxychlor Solid solution catalyst containing iron cations for the oxychlor

1976-11-15

1978-10-10

Shine, W. J.

Compositions

Preservative agents

Anti-oxidants or chemical change inhibitants

252462, 252470, B01J 2104, B01J 2310, B01J 2374

Patent

active

041195701

ABSTRACT:
An alkane is reacted with oxygen and available chlorine in the presence of a solid solution catalyst containing iron cations to yield unsaturated hydrocarbons and chlorinated saturated and unsaturated hydrocarbons. In a preferred embodiment of the process, ethane is reacted with oxygen and available chlorine in the presence of a solid solution catalyst containing iron cations to yield vinyl chloride, ethylene, and other valuable by-products. The conversion of ethane to products approaches 100 percent, vinyl chloride is prepared in up to 40 mole percent yield, and the combined yield of vinyl chloride, ethylene dichloride, ethyl chloride, and ethylene is up to 90 mole percent.

REFERENCES:
patent: 3420901 (1969-01-01), Schulz
patent: 3957691 (1976-05-01), Abachi et al.

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