Solid phase host compositions

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

Reexamination Certificate

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C556S449000, C556S450000, C556S465000

Reexamination Certificate

active

07915438

ABSTRACT:
A new family of silicon-based polymers has been prepared in which organic host components are bound covalently. The polymer is a polysilsesquioxane matrix comprising, for example, hosts such as cyclodextrins (CD) or calixarenes (CX).

REFERENCES:
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Kimura et al. {Bull. Chem. Soc. Jpn., 71 (1998), pp. 657-660.}.
Narumi et al. {Tetrahedron Letters, 43 (2002), pp. 621-625)}.
Lambert, J.B., Liu, C., Boyne, M.T., Zhang, A.P., and Yin, Y., Solid Phase Host—Guest Properties of Cyclodextrins and Calixarenes Covalently Attached to a Polysilsesquioxane Matrix, Chem. Mater. 2003, 15, pp. 131-145.
Huq, R., Mercier, L., and Kooyman, P.J., Incorporation of Cyclodextrin into Mesostructured Silica, Chem. Mater, 2001, 13, pp. 4512-4519.
Mayr, B., Sinner, F., Buchmeiser, M.R., Chiral β-Cyclodextrin-Based Polymer Supports Prepared via Ring-Opening Metathesis Graft-Polymerization, J. Chromatoophy A, 907 (2001) 47-56.
Ciucanu, I.; Selective Immoblization on Silica Gel of Permethylated β-cyclodextrin for Liquid Chromatography, J. Chromatography A (1996) vol. 727 pp. 195-201.

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