Chemistry: electrical current producing apparatus – product – and – Fuel cell – subcombination thereof – or method of making or... – Fuel cell with solid electrolyte
Reexamination Certificate
2007-03-28
2011-11-15
Menon, Krishnan S (Department: 1777)
Chemistry: electrical current producing apparatus, product, and
Fuel cell, subcombination thereof, or method of making or...
Fuel cell with solid electrolyte
C429S484000, C429S485000, C429S486000, C429S487000, C429S488000, C429S490000, C429S502000, C429S505000
Reexamination Certificate
active
08057951
ABSTRACT:
Conveying gas containing sulfur through a sulfur tolerant planar solid oxide fuel cell (PSOFC) stack for sulfur scrubbing, followed by conveying the gas through a non-sulfur tolerant PSOFC stack. The sulfur tolerant PSOFC stack utilizes anode materials, such as LSV, that selectively convert H2S present in the fuel stream to other non-poisoning sulfur compounds. The remaining balance of gases remaining in the completely or near H2S-free exhaust fuel stream is then used as the fuel for the conventional PSOFC stack that is downstream of the sulfur-tolerant PSOFC. A broad range of fuels such as gasified coal, natural gas and reformed hydrocarbons are used to produce electricity.
REFERENCES:
patent: 4920015 (1990-04-01), Sammells
patent: 5021304 (1991-06-01), Ruka et al.
patent: 5589285 (1996-12-01), Cable et al.
patent: 5753385 (1998-05-01), Jankowski et al.
patent: 6238816 (2001-05-01), Cable et al.
patent: 6946209 (2005-09-01), Israelson
patent: 2003/0180602 (2003-09-01), Finn et al.
patent: 2003/0211375 (2003-11-01), Ruhl
patent: 2004/0086772 (2004-05-01), Chianelli et al.
patent: 2005/0074650 (2005-04-01), Sridhar et al.
patent: 2007/0259228 (2007-11-01), Hartvigsen et al.
patent: 2008/0138669 (2008-06-01), Bayless et al.
patent: 2011/0014526 (2011-01-01), Gur
Aguilar et al.; Sulfur-Tolerant Materials for the Hydrogen Sulfide SOFC; manuscript; 2004; A324-A326; Electrochemical and Solid State Letters 7 (10).
Aguilar; Sulfur-Tolerant Materials for the Hydrogen Sulfide Solid Oxide Fuel Cell; Thesis; 2004.
Aguilar et al.; A Solid Oxide Fuel Cell Operating on Hydrogen Sulfide (H2S) and Sulfur-Containing Fuels; Journal of Power Sources; 2004; 17-24.
Badwal, S.P.S.; Stability of Solid Oxide Fuel Cell Components; Solid State Ionics 143; 2001; 39-46.
Bayless, David J.; Adapting Planar Solid Oxide Fuel Cells for use with Solid Fuel Sources in the Production of Distributed Power.
Dees et al.; Interfacial Effects in Monolithic Solid Oxide Fuel Cells; symposium; 1989; 317-321.
Gamson et al.; Sulfur from Hydrogen Sulfide; Chemical Engineering Progress Journal 49; 1953; 203-215.
Geyer et al.; Investigations into the Kinetics of the Ni-YSZ-Cermet Anode of a Solid Oxide Fuel Cell; Electrochemical Proceedings vol. 97-18; 584-595.
Jiang et al.; Fuel Composition and Diluent Effect on Gas Transport and Performance of Anode-Supported SOFCs; manuscript; Journal of the Electrochemical Society, 150 (7); 2003; A942-A951.
Kirk et al.; A Hydrogen Sulfide Solid-Oxide Fuel Cell Using Ceria-Based Electrolytes; J. Electrochem. Soc., vol. 140, No. 12; 1993; 3494-3496.
Kohler et al.; Sulfur Oxidation Kinetics on Pt(111) at Low and High Sulfur Coverages; Surface Science Journal 136; 1984; 243-256.
Liu et al.; Performance of a Solid Oxide Fuel Cell Utilizing Hydrogen Sulfide as Fuel; Journal of Power Sources 94; 2001; 20-25.
Marina et al.; Thermal, Electrical, and Electrocatalytical Properties of Lanthanum-Doped Strontium Titanate; Solid State Ionics 149; 2002; 21-28.
Matsuzaki et al.; The Poisoning Effect of Sulfur-Containing Impurity Gas on a SOFC Anode: Part I. Dependence on Temperature, Time and Impurity Concentration; Solid State Ionics 132; 2000; 261-269.
Mukundan et al.; Sulfur Tolerant Anodes for SOFCs; Electrochemical and Solid-State Letters 7 (1); 2004; A5-A7.
Peterson et al.; Utilization of Hydrogen Sulfide in an Intermediate-Temperature Ceria-Based Solid Oxide Fuel Cell; J. Electrochem. Soc., vol. 145, No. 5; 1998; 1449-1454.
Pudmich et al.; Chromite/Titanate Based Perovskites for Application as Anodes in Solid Oxide Fuel Cells; Solid State Ionics 135; 2000; 433-438.
Pujare et al.; A Direct H2S/Air Solid Oxide Fuel Cell; J. Electrochem. Soc.; 1987; 2639-2640.
Pujare et al.; An Electrochemical Claus Process for Sulfur Recovery; J. Electrochem. Soc., vol. 136, No. 12; 1989; 3662-3678.
Steijns et al.; The Role of Sulfur Trapped in Micropores in the Catalytic Partial Oxidation of Hydrogen Sulfide with Oxygen; Journal of Catalysis 35; 1974; 11-17.
Suwanwarangkul et al; Performance Comparison of Fick's, Dusty-Gas and Stefan-Maxwell Models to Predict the Concentration Overpotential of a SOFC Anode; Journal of Power Sources 122; 2003; 9-18.
Trembly et al.; Effects of Coal Syngas and H2S on the Performance of Solid Oxide Fuel Cells: Single-Cell Tests; Journal of Power Sources 158; 2006; 263-273.
Yakabe et al.; Evaluation and Modeling of Performance of Anode-Supported Solid Oxide Fuel Cell; Journal of Power Sources 86; 2000; 423-431.
Yamamoto, Osamu; Solid Oxide Fuel Cells: Fundamental Aspects and Prospects; Electrochimica Acta 45; 2000; 2423-2435.
Yates et al.; Anode Materials for a Hydrogen Sulfide Solid Oxide Fuel Cell; Journal of the Electrochemical Society 146 (8); 1999; 2841-2844.
Yentekakis et al.; Chemical Cogeneration in Solid Electrolyte Cells; J. Electrochem. Soc., vol. 136, No. 4; 1989; 996-1002.
Zhu et al.; A General Mathematical Model for Analyzing the Performance of Fuel-Cell Membrane-Electrode Assemblies; Journal of Power Sources 117; 2003; 61-74.
Bayless David J.
Cooper Matthew Ellis
Trembly Jason P.
Foster Jason H.
Kremblas & Foster
Menon Krishnan S
Ohio University
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