Solid contact system for potentiometric sensors

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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204416, 257253, G01N 27333

Patent

active

058977589

ABSTRACT:
An improvement to the coated wire electrode has been accomplished via inclusion of a fortiophore into a sensor device. Sensor devices of the present invention include: an internal reference element; a membrane; and a fortiophore. Fortiophores are neutral charge carriers, which complex reversibly a corresponding ion of the conductive material used as the internal reference element. The fortiophore provides an electrochemically defined and reproducible solid internal contact between the membrane and the internal reference element. This solid internal contact, for example, in ion selective sensors, provides more reproducible potential offsets and better precision, and faster wet up. The fortiophores can be utilized in other electrochemical devices.

REFERENCES:
patent: 4361473 (1982-11-01), Young et al.
patent: 4735702 (1988-04-01), Reinhoudt et al.
patent: 4871442 (1989-10-01), Yamaguchi et al.
Karl Cammann, Working with Ion-Selective Electrodes, Springer-Verlag, Berlin, 1979 a month of publication not available, pp. 31-48.
Arthur K. Covington, editor, Ion-Selective Electrode Methodology, vol. 1, CRC Press, Inc., Boca Raton, Florida, USA, 1979 a month of publication not available, pp. 58-62.

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