Solid catalyst component for the polymerization of olefins and a

Details Solid catalyst component for the polymerization of olefins and a Solid catalyst component for the polymerization of olefins and a

1988-12-23

1990-11-13

Garvin, Patrick P.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Plural component system comprising a - group i to iv metal...

526124, C08F 4649

Patent

active

049701860

ABSTRACT:
A solid catalyst component prepared by admixing and reacting, with a reaction product which has been obtained by suspending diethoxymagnesium in an alkylbenzene and bringing the suspension into contact with titanium tetrachloride in an amount less than 1 in terms of volume ratio to the alkylbenzene, a phthaloyl dichloride at a temperature within the range between 80.degree. C. and 125.degree. C., washing the resultant solid substance with an alkylbenzene, and reacting the solid substance in the presence of an alkylbenzene with titanium tetrachloride in an amount less than 1 in terms of volume ratio to the alkylbenzene as well as an olefin polymerization catalyst which comprises (A) the above specified solid catalyst component, (B) a silicon compound of the general formula: SiR.sub.m (OR').sub.4-m wherein R is a group selected from an alkyl group, a cycloalkyl group, an aryl group and vinyl group, R' is an alkyl group and m is zero or an integer of 1-3, with the proviso that when m is 2 or 3, plural R groups may be identical or different, that when m is zero or 1, plural R' groups may be identical or different and/or that when R is an alkyl group, R may be identical with or different from R', and (C) an organoaluminum compound of the general formula: R".sub.n AlX.sub.3-n wherein R" is an alkyl group, X is a halogen atom and n is an integer of 1-3, with the proviso that when n is 2 or 3, plural R" groups may be identical or different. This catalyst exhibits an extremely high polymerization activity combined with a high stereospecific performance and enables the production of stereoregular olefin polymers with a negligible residual chlorine content in a high yield.

REFERENCES:
patent: 4565798 (1986-01-01), Yamamoto et al.
patent: 4579919 (1986-04-01), Staiger et al.
patent: 4710482 (1987-12-01), Job
patent: 4780443 (1988-10-01), Matsuura et al.
patent: 4804648 (1989-02-01), Job

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