Chemistry: electrical current producing apparatus – product – and – With pressure equalizing means for liquid immersion operation
Reexamination Certificate
2002-08-01
2008-08-26
Crepeau, Jonathan (Department: 1795)
Chemistry: electrical current producing apparatus, product, and
With pressure equalizing means for liquid immersion operation
C204S295000, C095S055000, C423S305000, C423S306000, C423S308000, C423S312000
Reexamination Certificate
active
07416803
ABSTRACT:
Improved solid acid electrolyte materials, methods of synthesizing such materials, and electrochemical devices incorporating such materials are provided. The stable electrolyte material comprises a solid acid capable undergoing rotational disorder of oxyanion groups and capable of extended operation at elevated temperatures, that is, solid acids having hydrogen bonded anion groups; a superprotonic, trigonal, tetragonal, or cubic, disordered phase; and capable of being operating at temperatures of ˜100° C. and higher.
REFERENCES:
patent: 4632847 (1986-12-01), Lomasney et al.
patent: 4659559 (1987-04-01), Struthers
patent: 4664683 (1987-05-01), Degen et al.
patent: 4836911 (1989-06-01), Skeels, Gary W. et al.
patent: 4985315 (1991-01-01), Lemoine
patent: 5260821 (1993-11-01), Chu et al.
patent: 5308808 (1994-05-01), Gregar et al.
patent: 5344548 (1994-09-01), Alberti et al.
patent: 5436094 (1995-07-01), Horimoto et al.
patent: 5506075 (1996-04-01), Iwasaki et al.
patent: 5559638 (1996-09-01), Aoki et al.
patent: 5573648 (1996-11-01), Shen et al.
patent: 5576115 (1996-11-01), Capuano et al.
patent: 5591545 (1997-01-01), Miyashita et al.
patent: 5682261 (1997-10-01), Takada et al.
patent: 5766799 (1998-06-01), Hong
patent: 5840375 (1998-11-01), Katsumi et al.
patent: 6001507 (1999-12-01), Ono et al.
patent: 6059943 (2000-05-01), Murphy et al.
patent: 6121727 (2000-09-01), Kanai et al.
patent: 6153333 (2000-11-01), Barker
patent: 6468684 (2002-10-01), Chisholm et al.
patent: 7125621 (2006-10-01), Haile et al.
patent: 2007/0009778 (2007-01-01), Chisholm et al.
patent: 3110571 (1982-09-01), None
patent: 0702376 (1996-03-01), None
patent: 0818841 (1998-01-01), None
patent: 63 239781 (1988-10-01), None
patent: WO 00/45447 (2000-08-01), None
Alberti, et al., “Solid State Protonic Conductors, Present Main Applications and Future Prospects,”Solid State Ionics, Mar. 20, 2001, pp. 3-16, vol. 145, Elsevier Science B.V.
Boysen, et al., “Polymer Solid Acid Composite Membranes for Fuel-Cell Applications,”Journal of the Electrochemical Society, 2000, pp. 3610-3613, vol. 147, The Electrochemical Society, Inc.
Chisholm, et al., “Structure and Thermal Behavior of the New Superprotonic Conductor Cs2(HSO4)(H2PO4),”Acta Crystallographica, 1999, pp. 937-946, Section B55, International Union of Crystallography, Great Britain.
Chisholm, et al., “Superprotonic Behavior of Cs2(HSO4)(H2PO4)—A New Solid Acid in the CsHSO4-CsH2PO4System,”Solid State Ionics, 2000, pp. 229-241, vols. 136-137, Elsevier Science B.V.
Chisholm, et al., “Superprotonic Phase Transition in CsH(PO3H),”Chemistry Materials, Mar. 20, 2002.
Chisholm, et al., “Synthesis, Structure, and Properties of Compounds in the NaHSO4-CsHSO4System. 1. Crystal Structures of Cs2Na(HSO4)3and CsNa2(HSO4)3,”Chemistry Materials, Jul. 17, 2001, pp. 2574-2583, vol. 13, No. 8, American Chemical Society.
Chisholm, et al., Synthesis, Structure, and Properties of Compounds in the NaHSO4-CsHSO4System. 2. The Absence of Superprotonic Transitions in Cs2Na(HSO4)3and CsNa2(HSO4)3,Chemistry Materials, Aug. 21, 2001, pp. 2909-2912, vol. 13, No. 9, American Chemical Society.
Cooksley, et al., “Crystal Structure of Monoclinic NaCaHSiO4,”Acta Crystallographica, Apr. 15, 1974, pp. 864-867, Section B30, Part 4, International Union of Crystallography, Great Britain.
Felsche, et al., “Thermal Studies on Sodium Silicate Hydrates. II. Disodium Dihydrogensilicate Hydrates, Na2H2Si2SiO4-nH2O(n=4, 5, 7, 8): Melting Characteristics and Solidification of Glasslike Hydrate Phases at Low Temperatures,”Thermochimica Acta., Jun. 15, 1984, pp. 109-121, vol. 77, Nos. 1-3, Elsevier Science B.V.
Haile, “Hydrogen Bonding and Phase Transitions in Proton-Conducting Solid Acids,”Mat. Res. Soc. Symp. Proc., 1999, pp. 315-326, vol. 547.
Haile, et al., “Single-Crystal Neutron Diffraction Study of β-Cs3(HSO4)2[H2-x(SxP1-x)O4] (x≃0.5) at 15 K,”Acta Crystallographica, 1999, pp. 285-296, Section B55, International Union of Crystallography, Great Britain.
Haile, et al., “Solid Acids as Fuel Cell Electrolytes,”Nature, Apr. 19, 2001, pp. 910-913, vol. 410.
Haile, et al., “Structure and Vibrational Spectrum of β-Cs3(HSO4)2[H2-x(P1-xSx)O4] (x˜0.5) a New Superprotonic Conductor, and a Comparison with α-Cs3(HSO4)2(H2PO4),”Journal of Solid State Chemistry, 1998, pp. 373-387, vol. 139, Academic Press.
Haile, et al., “X-Ray Diffraction Study of Cs5(HSO4)3(H2PO4)2a New Solid Acid with a Unique Hydrogen-Bond Network,”Journal of Solid State Chemistry, 1998, pp. 251-265, vol. 140, Academic Press.
Lavrova, et al., “Disordering of Pentacesium Trihydrogen Tetrasulfate in Cs5H3(SO4)4-SiO2Composite Proto Electrolytes,” Inorganic Materials, 2002, vol. 38, No. 11, pp. 1172-1177.
Ponomareva, et al., “Effect of SiO2morphology and pores size on the proton nanocomposite electrolytes properties,” Solid State Ionics, 1999, 119, pp. 295-299.
Ponomareva, et al., “Composite protonic solid electrolytes in CsHSO4-SiO2system,” State Ionics, 1996, 90, pp. 161-166.
Ponomareva, et al., “The influence of heterogeneous dopant porous structure on the properties of protonic solid electrolyte in the CsHSO4-SiO2system,” Solid State Ionics, 1999, 118, pp. 317-323.
Ponomareva, et al., “Composite protonic electrolytes in the system (NH4)3H(SO4)2-SiO2,” Solid State Ionics, 2001, 145, pp. 205-210.
Ponomareva, et al., “The investigation of disordered phases in nanocomposite proton electrolytes based on MeHSO4(Me=Rb, Cs,K),” Solid State Ionics, 2001, 145, pp. 197-204.
Jamieson, et al., “Sodium Silicate Hydrates. I. Crystallographic Data,”Acta Crystallographica, Mar. 10, 1996, pp. 373-376, vol. 20, Part 3, International Union of Crystallography, Great Britian.
Lewis, “Hawley's Condensed Chemical Dictionary,” Thirteenth Edition, p. 910, John Wiley & Sons, Inc. (1997)
Meunier, et al., “Pulsed Laser Deposition of Superionic Ceramic Thin Films: Deposition and Applications in Electrochemistry,”Applied Surface Science, 1998, pp. 466-470, vol. 127-129, Elsevier Science B.V.
Mhiri, “Hydrogen Bonding in Cs1-xMxHSO4Protonic Conductors,”Solid State Ionics, May. 1993, pp. 187-191, vol. 61, No. 1-3, Elsevier Science B.V.
Münster, et al., “Periodical for Inorganic and General Chemistry,”Notebook 5-6, Nov. 1965, pp. 225-360, vol. 340, Johann Ambrosius Barth Publishing, Leipzig.
Pfeiffer, et al., “Synthesis of Lithium Silicates,”Journal of Nuclear Materials, 1998, pp. 309-317, vol. 257, Elsevier Science B.V.
Politova, et al., “Ethylene Hydrogenation in Electrochemical Cell with Solid Proton-Conducting Electrolyte,”Reaction Kinetics&Catalysis Letters, 1990, pp. 321-326, vol. 41, No. 2, Elsevier Science B.V.
Gargouri, M. et al., “Phase Transitions and Electrical Properties of CSH(SO4)(SeO4) Mixed Crystals,” October 1997, Solid State Ionics, vol. 100, Nos. 3,4, pp. 225-232.
Haile. S. M. et al., “Superprotonic Conductivity in Cs3(HSO4)(H2PO4),”1995, Solid State Ionics, vol. 77, pp. 128-134.
Ohi, K. et al., “Ferroelectric Phase Transition in Rb2So4-(NH4)2SO4 and Cs2SO4-(NH4)2SO4 Mixed Crystals,” Feb. 1978, Journal of the Physical Society of Japan, 44(2), pp. 529-536.
Volkov, V. L., et al., “Cesium Ammonium Dihadrogen Arsenate Hydrates,” Apr. 1997, Inorganic Materials (Translations of Neogranicheskie Materialy) 33(4), 496-499.
Zaidi, S. M. J. et al., “Solid Polymer Composite Electrolytes for PEMFC,” 1998,Proc. Intersoc. Energy Convers. Eng. Conf., vol. 33.
Boysen Dane A.
Chisholm Calum
Haile Sossina M.
Merle Ryan B.
Narayanan Sekharipuram R.
California Institute of Technology
Crepeau Jonathan
Townsend and Townsend / and Crew LLP
LandOfFree
Solid acid electrolytes for electrochemical devices does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Solid acid electrolytes for electrochemical devices, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Solid acid electrolytes for electrochemical devices will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-4002987