Solid acid alkylation using a sulfated mixed oxide of titanium/n

Chemistry of hydrocarbon compounds – Saturated compound synthesis – By condensation of a paraffin molecule with an olefin-acting...

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502222, 502337, 502350, 585721, C07C 258

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053450280

ABSTRACT:
Disclosed is an alkylation catalyst to form adducts or alkylates of a C.sub.3 -C.sub.9 olefin with a C.sub.4 to C.sub.9 isoparaffin comprising a sulfated mixed oxide of titanium and nickel, wherein the percent by weight of titanium is at least 80%; of nickel is in the range 1-4%; and of sulfur in the range 1-10%. Also disclosed are the appropriate ratios of olefin to isoparaffin and the use of adamantane to increase yields.

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"Effect of Acid Strength on the Catalytic Activity of NiO-TiO.sub.2 Modified with Acids", by J. R. Sohn, et al., Journal of Catalysis, 127, 449-452 (1991).
"New Solid Acids and Bases", K. Tanabe et al., Studies in Surface Science and Catalysis, vol. 51 pp. 199-213.

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