Sol-gel derived lead oxide containing ceramics

Compositions: ceramic – Ceramic compositions – Titanate – zirconate – stannate – niobate – or tantalate or...

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501 12, 252 629, 423593, 423598, 423608, 423610, C04B 3549

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active

053842944

ABSTRACT:
Method is provided for preparing PbO-based ceramics by mixing metal cations in alkanolamines and then adding the mixture to lead carboxylates in alcohol, to obtain ceramic solutions or gels therefrom. The metal cations are sourced from metal alkoxides, chelates and salts and include metals of Ti, Zr and La. The above solutions and gels can be employed to form PbO-based powders, fibers and films, e.g. films of PZT and PLZT, which find electrical and optical applications such as ferroelectric memory and dielectric waveguides. The invention resides in the above method and resulting PbO ceramics which have e.g. films of considerably higher dielectric constants than previously known in the art.

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