Stock material or miscellaneous articles – Composite – Of inorganic material
Reexamination Certificate
1995-06-07
2001-10-16
Kiliman, Leszek (Department: 1773)
Stock material or miscellaneous articles
Composite
Of inorganic material
C428S690000, C428S900000, C420S128000, C420S462000, C148S306000, C148S318000
Reexamination Certificate
active
06303240
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to a soft magnetic thin film useful for example for a core material for a magnetic head.
BACKGROUND
In a magnetic recording and/or reproducing apparatus, such as an audio tape recorder or a video tape recorder (VTR), the tendency is towards increasing the recording density and the quality of the recording signals. In keeping with such tendency towards increasing the recording density, a so-called metal tape in which powders of metals such as Fe, Co or Ni or alloys thereof are used as magnetic powders, or a so-called vapor-deposited tape in which a magnetic metal material is directly applied to a base film by a vacuum thin film forming technique, has been developed as the magnetic recording medium, and put into practical use in many fields.
PROBLEMS IN THE ART
For exhibiting the properties of the magnetic recording medium having predetermined coercivities, the core material of the magnetic head need to exhibit a high saturated magnetic flux density and, when the same magnetic head is also used for reproduction, the core material also need to exhibit high magnetic permeability simultaneously. However, the ferrite material used frequently as the core material of the magnetic head has a low saturated magnetic flux density, whereas the permalloy is poor in wear resistance.
As the core material satisfying these various requirements, a Sendust alloy composed of an Fe—Al—Si alloy has been devised so being a suitable material, and put to practical use.
It is however desirable for a material exhibiting superior soft magnetic properties, such as the Sendust alloy, to exhibit magnetostriction &lgr;s and crystal magnetic anisotropy K which are both close to zero. Thus the composition of a material that may be used in a magnetic head is determined with both of these two parameters taken into consideration. In this manner, the saturated magnetic flux density is unequivocally determined as a function of the composition and, in case of the Sendust alloy, the limit of the saturated magnetic flux density is set to 10 to 11K gauss.
For this reason, a Co base amorphous magnetic alloy material, so-called amorphous magnetic alloy material, which is hardly lowered in permeability in the high frequency range while exhibiting a high saturated magnetic flux density, has been developed to take the place of the Sendust alloy. However, with this amorphous magnetic alloy material, the saturation magnetic flux density is in the order of 14K gauss.
SUMMARY OF THE DISCLOSURE
It is an object of the present invention to provide a novel soft magnetic thin film having a saturated magnetic flux density higher than that of the above mentioned conventional materials.
According to the present invention, the above mentioned object may be accomplished by a soft magnetic thin film having a compositional formula Fe
a
B
b
N
c
, wherein a, b and c each denote atomic percent and B denotes at least one of Co, Ni and Ru, and wherein the compositional range is given by
0<b≦5,
and
0<c≦5.
In a preferred embodiment, the soft magnetic thin film exhibits uniaxial anisotropy.
The soft magnetic thin film of the present invention contains Fe and N, and at least one of the specific additional elements “B”, i.e., Co, Ni or Ru in the predetermined compositional range aforementioned, so that it exhibits a high saturated magnetic flux density, such as B
25
>14 kG, and a low coercivity. The soft magnetic thin film of the present invention can also be of uniaxial anisotropy. Hence, it may be used advantageously as a magnetic head core material.
PREFERRED EMBODIMENTS
The soft magnetic thin film of the present invention contains Fe, N and a specified additional element or elements termed “B”, that is at least one of Co, Ni and Ru, wherein Fe, N and the additional element or elements B are within the above specified compositional range.
Since N and the specified additional elements B are contained in amounts of not more than 5 atomic percent, the coercivity Hc is low (Hc<4 Oe) while a saturation magnetic flux density Bs of not less than a predetermined value of about 16 kG is maintained.
Although the additional element B exhibits a significant effect when contained in an amount of, for example, 0.1 atomic percent, it is contained preferably in an amount of not less than 0.5 atomic percent, more preferably in an amount of 1 atomic percent. When the additional element exceeds 5 atomic percent, the coercivity Hc occasionally exceeds a desired value, so that the additional element(s) are contained in an amount of not more than 5 atomic percent.
Although N exhibits an effect of a practical meaning when contained in an amount of 0.1 atomic percent, it is preferably contained in an amount of not less than 0.5 atomic percent. When N is contained in an amount in excess of 5 atomic percent, the coercivity occasionally exceeds a desired value, so that N is contained in an amount of not more than 5 atomic percent.
Preferably, the soft magnetic thin film of the present invention exhibits uniaxial anisotropy. In this case, by having the hard axis for magnetization of the thin film as the direction of magnetization, it is possible to increase the permeability at a frequency higher than 1 MHz sufficiently. Therefore, the film is highly useful as the magnetic head core material. For obtaining high permeability at higher frequencies, it is necessary to provide uniaxial anisotropy preferably not lower than 1 Oe and more preferably in the order of 2 to 5 oe in terms of the strength of the anisotropic magnetic field. When high permeability is desired at not lower than, for example, 10 MHz, the desired value of uniaxial anisotropy is in the order of 3 to 5 Oe.
The additional element(s) “B” are one or more of Co, Ni and Ru.
For producing the soft magnetic thin film of the present invention, the thin film of the above mentioned specified composition is produced by a vapor deposition method, such as the RF sputtering method, and heat treating (or annealing) the thin film preferably at 220° to 450° C., for partially or wholly crystallizing the thin film in the case where the thin film is amorphous. The average crystal grain size of the heat treated (annealed) thin film is preferably not more than 50 nm (500 Å) and more preferably not more than 30 nm (300 Å). When heat treatment is performed at a temperature lower than 220° C. or exceeding 450° C., it would occasionally fail to produce a soft magnetic thin film of the desired low coercivity. More preferably, the above mentioned heat treatment is performed in a magnetic field to induce uniaxial magnetic anisotropy for partially or entirely crystallizing the thin film. The above mentioned magnetic field is preferably sufficiently larger than the demagnetizing field of the thin film.
When the soft magnetic thin film is formed on a base plate by the above mentioned method, various properties of the produced soft magnetic films may vary occasionally from one base plate to another depending on the kind. Therefore, it is more desirable to make proper selection of the base plate prior to the preparation of the thin film.
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Magnetics Properties of Amorphous Fil
Nakanishi Kanji
Shimizu Osamu
Fuji Photo Film Co. , Ltd.
Kiliman Leszek
Sughrue Mion Zinn Macpeak & Seas, PLLC
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