Sodium to sodium carbonate conversion process

Hazardous or toxic waste destruction or containment – Destruction or containment of radioactive waste – Chemical conversion to a stable solid for disposal

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423189, 423246, 423421, G21F 900

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active

056782403

ABSTRACT:
A method of converting radioactive alkali metal into a low level disposable solid waste material. The radioactive alkali metal is atomized and introduced into an aqueous caustic solution having caustic present in the range of from about 20 wt % to about 70 wt % to convert the radioactive alkali metal to a radioactive alkali metal hydroxide. The aqueous caustic containing radioactive alkali metal hydroxide and CO.sub.2 are introduced into a thin film evaporator with the CO.sub.2 present in an amount greater than required to convert the alkali metal hydroxide to a radioactive alkali metal carbonate, and thereafter the radioactive alkali metal carbonate is separated from the thin film evaporator as a dry powder. Hydroxide solutions containing toxic metal hydroxide including one or more metal ions of Sb, As, Ba, Be, Cd, Cr, Pb, Hg, Ni, Se, Ag and T1 can be converted into a low level non-hazardous waste using the thin film evaporator of the invention.

REFERENCES:
patent: 3773902 (1973-11-01), Neumann
patent: 3819813 (1974-06-01), Jones, Jr. et al.
patent: 3842157 (1974-10-01), Neumann
patent: 3975503 (1976-08-01), Hauschild et al.
patent: 4895678 (1990-01-01), Ohtsuka et al.
patent: 5348689 (1994-09-01), Gay et al.
Herrmann et al., "Elemental Sodium to Sodium Carbonate Conversion at Argonne National Laboratory" Presentation at American Nuclear Society Meeting Jun. 25 thru 29th, 1995, 7 pages.

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