Slurry activation of Fischer-Tropsch catalyst with carbon...

Chemistry: fischer-tropsch processes; or purification or recover – Including regeneration of catalyst

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C518S700000, C518S720000

Reexamination Certificate

active

07001928

ABSTRACT:
Methods and apparatus for improving the efficiency and effectiveness of in situ reduction of a Fischer-Tropsch catalyst slurry. The preferred embodiments of the present invention are characterized by a system that utilizes a co-feed of carbon monoxide along with the reducing gas into a reduction vessel maintained at an elevated temperature. As the metal oxide reduces to the active Fischer-Tropsch metal, the carbon monoxide acts as a poison to hydrogenolysis and reduces the loss of liquid from the slurry and the production of methane. The carbon monoxide is generally in parts-per-million quantities and will achieve the desired results in quantities less than 5,000 ppm, preferably less than 2,000 ppm.

REFERENCES:
patent: 2540109 (1951-02-01), Friedman
patent: 2608568 (1952-08-01), Hogan et al.
patent: 4595703 (1986-06-01), Payne et al.
patent: 4626552 (1986-12-01), Arcuri
patent: 4738948 (1988-04-01), Iglesia et al.
patent: 4822824 (1989-04-01), Iglesia et al.
patent: 5260239 (1993-11-01), Hsia
patent: 5389690 (1995-02-01), Mitchell
patent: 5728918 (1998-03-01), Nay et al.
patent: 5958986 (1999-09-01), Mart et al.
patent: 6022755 (2000-02-01), Kinnari et al.
patent: 6043288 (2000-03-01), DeGeorge et al.
patent: 6066679 (2000-05-01), Leviness et al.
patent: 6147126 (2000-11-01), DeGeorge et al.
patent: 6475943 (2002-11-01), Hoek et al.
patent: 6486220 (2002-11-01), Wright
patent: 6703430 (2004-03-01), Culross
patent: 6753351 (2004-06-01), Clark et al.
Jongsomjit, Bunjerd, et al;Co-Support Compound Formation in Co/Al2O3Catalysts: Effect of Reduction Gas Containing CO: Catalysis Today 77 (2002) 191-204.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Slurry activation of Fischer-Tropsch catalyst with carbon... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Slurry activation of Fischer-Tropsch catalyst with carbon..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Slurry activation of Fischer-Tropsch catalyst with carbon... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3704711

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.