Skin cleansing gel having a heating effect

Details Skin cleansing gel having a heating effect Skin cleansing gel having a heating effect

2002-08-30

2003-11-04

Venkat, Jyothsna (Department: 1615)

Drug, bio-affecting and body treating compositions

Preparations characterized by special physical form

Cosmetic, antiperspirant, dentifrice

C424S685000, C424S698000, C424S709000

Reexamination Certificate

active

06641825

ABSTRACT:

FIELD OF THE INVENTION
This invention relates to a gentle skin cleansing gel which, for use, is mixed with water and releases heat in the process. The heat released creates a sensorially pleasant impression on the skin, improves the cleansing effect, enhances the release of perfumes and leads to an improved effect of the skin-care ingredients present.
BACKGROUND OF THE INVENTION
The use of water-free salts with a negative enthalpy of solution which release heat of hydration when dissolved in water for the production of cosmetic preparations which heat up in use has been repeatedly described. DE 2317140 C2 describes water-based skin and hair treatment preparations which are heated just before use by addition of calcium chloride or magnesium sulfate. DE 19624870 A1 and WO 97102802 A2 describe dental care preparations which release heat on contact with water or saliva during brushing of the teeth. WO 93/08793 A1 describes a skin cleanser which may be used, for example, as a face mask and which contains a dehydrated molecular sieve in a water-free carrier as heat-releasing component.
However, these known preparations are unsuitable for use as skin cleansers, for example in the form of liquid or paste-form preparations of the liquid soap or washing paste type because they do not generate enough foam so that satisfactory cleansing of even relatively heavily soiled skin is not achieved.
Accordingly, there was a need to develop a skin cleanser in the form of a liquid or high-viscosity gel-form preparation which could be used like a normal liquid soap or a hand washing paste and which, in use, would generate a rich foam and at the same time so much heat that a sensorially pleasant feeling on the skin and deep-pore cleansing of the skin would be obtained.
SUMMARY OF THE INVENTION
The problem stated above has been solved by a cleansing gel which releases heat of hydration when mixed with water and which consists of a water-free liquid carrier and powder components dispersed therein, characterized in that it contains
(A) at least 40% by weight of water-miscible hydroxyl compounds selected from glycols, glycol ethers and polyols containing 2 to 6 carbon atoms, polyalkylene glycols with molecular weights of up to 1,000 D and mixtures thereof,
(B) at least 5% by weight of anionic, zwitterionic, amphoteric or nonionic surfactants,
(C) at least 5% by weight of dispersed, particulate, water-soluble salts with a negative enthalpy of solution (in water) and
(D) at least 0.1% by weight of a water-soluble thickener dissolved in the carrier or at least 1% by weight of a particulate thickener dispersed in the carrier or both.
DETAILED DESCRIPTION OF THE INVENTION
In the context of the invention, a carrier liquid is regarded as water-free if it contains so little water that the hydrating salts dispersed therein do not undergo significant hydration.
Water-miscible hydroxyl compounds in the context of the invention are, above all, glycols, glycol ethers and polyols containing 2 to 6 carbon atoms. Accordingly, suitable glycols are ethylene glycol, propanediols and butanediols. Suitable glycolethers are, for example, ethyl glycol, ethyl diglycol, diethylene glycol, triethylene glycol and dipropylene glycol. Suitable polyols are, for example, glycerol, erythritol, pentaerythritol, trimethylol propane, diglycerol and sorbitol. Suitable polyalkylene glycols are, for example, the liquid polyethylene glycols, the polypropylene glycols and the addition products of ethylene oxide onto propylene glycol or onto polypropylene glycols with molecular weights of up to 1,000 D. Monohydric alcohols such as ethanol or isopropanol, for example, may also be present in limited quantities of up to about 5% by weight.
These water-miscible hydroxyl compounds are preferably present in a quantity of 50 to 70% by weight of the cleansing gel. The consistency and the dissolving and dispersing behavior of the carrier can be influenced through the type and quantity of the water-miscible hydroxyl compounds. In addition, some of these hydroxyl compounds also have a negative enthalpy of mixing with water, i.e. heat is released on mixing with water. For this reason, it is preferred to use mixtures of two or more different hydroxyl compounds to obtain an optimal application profile. Mixtures of 1,2-propylene glycol, 1,3-butylene glycol, polyethylene glycol and ethoxydiglycol are particularly suitable carriers.
Suitable anionic surfactants are any surfactants of which the surface activity is attributable to an anion distinguished by a preferably linear alkyl or acyl group containing 10 to 18 carbon atoms which is linked to a sulfate, sulfonate, phosphate or carboxylate group. Particularly suitable anionic surfactants are foaming types such as, for example, the alkyl sulfates, the alkanesulfonates, the &agr;-olefin sulfonates, the acyl isethionates, the acyl taurides, the acyl sarcosides, the sulfosuccinic acid monoalkyl ester salts and the alkyl polyglycol ether carboxylates in the form of their alkali metal, magnesium, ammonium or alkanolammonium salts. Anionic surfactants obtainable in water-free fine-particle form are preferably used. These are generally the sodium salts of the anionic surfactants mentioned. Suitable zwitterionic surfactants are, above all, the betaine surfactants, for example C
12-18
alkyl dimethyl acetobetaine, cocoamidopropyl dimethyl acetobetaine, imidazolinium betaines and sulfobetaines containing a preferably linear C
10-18
alkyl or acyl group. Particularly suitable betaine surfactants are, above all, those obtainable in water-free, fine-particle form. A particularly suitable product is, for example, the cocoamidopropyl betaine marketed as Tego Betain CKD (N-N-dimethyl-N-lauroylamidopropyl)-ammoniumacetobetaine).
Ampholytic surfactants are understood to be surfactants which, besides a preferably linear C
8-18
alkyl or acyl group, contain a protonatable amino group and a carboxyl group and which are capable of forming inner salts. Suitable ampholytic surfactants are, for example, N-(C
12-18
)-alkyl-N-methyl glycine, N-(C
12-18
)-acylaminopropyl-N-methyl glycine, N-(C
12-18
)-acylaminoethyl-N-methyl glycine, N-(C
12-18
)-acylaminopropyl-N-hydroxyethyl glycine, 2-(C
12-18
)-alkyl carboxymethyl-3-hydroxyethyl imidazoline and 2-N-(C
8-18
)-alkylaminoethanecarboxylic acid.
Nonionic surfactants are surfactants which contain a lipophilic, preferably linear C
8-22
alkyl or acyl group and, as a hydrophilic group, a glucoside or polyglucoside group, a glycerol or polyglycerol group, a sorbitan group or a polyglycol ether group or several of these groups. Suitable nonionic surfactants are above all those which are available in water-free form, for example products of the addition of ethylene oxide onto fatty alcohols, fatty acids, fatty acid mono- or diglycerides, onto fatty acid alkanolamides, onto sorbitan fatty acid esters, onto methyl glucoside fatty acid esters or onto alkyl glucosides. Another particularly suitable group of nonionic surfactants are the silicone copolyols marketed, for example, under the name of Dow Corning Surfactant (Dow Corning) or Abil (Goldschmidt).
In one preferred embodiment, the cleansing gel according to the invention contains an anionic or zwitterionic surfactant or a mixture of such surfactants in a quantity of 10 to 30% by weight as surfactant.
Hydrating salts with negative enthalpy of solution are understood to be water-soluble salts which dissolve in water and release heat in the process. This is generally the case when hydrates are formed during dissolution and the heat of formation of these hydrates is greater than the heat consumed in overcoming the lattice energy. The hydrating salts are generally completely or partly dehydrated salts which form hydrates in water. Such salts are, for example, ortho- and pyrophosphates, carbonates and sesquicarbonate, borates, chlorides and sulfates of alkali metals, for example sodium. Other suitable salts are alkali metal citrates and acetates. Other suitable salts are zinc citrate, zinc sulfate, zinc nitrate, calcium chloride, calcium sulfate, ma

Affiliated with

Also associated with

Rating

Skin cleansing gel having a heating effect does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Skin cleansing gel having a heating effect, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Skin cleansing gel having a heating effect will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-3142733