Sintered parts made of oxygen-sensitive non-reducible powders an

Powder metallurgy processes – Powder metallurgy processes with heating or sintering – Powder pretreatment

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419 33, 419 36, 419 38, 419 41, 419 53, 419 54, B22F 316

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active

056049196

ABSTRACT:
The preferred sintered parts made of oxygen-sensitive, non-reducible powders and their production by injection-molding are distinguished by the powders used being freed of their oxide layer by attritor milling in a water-free organic solvent, in the presence or absence of an additional reductant, the oxide particles being removed if necessary by filtration or screening in the presence of the organic solvent, the oxide-free powder being mixed as suspension with a polyacetal as binder under a protective gas, the organic solvent being distilled off, the mixture of powder and polyacetal being heated above the melting point of the polyacetal and being compounded to give a homogeneous composition, the granular material thus obtained being processed in an injection-molding machine made inert with argon to give shaped bodies, the shaped bodies being freed of binder under the action of oxalic acid in a closed ceramic container which nevertheless allows pressure equilibration under protective gas at atmospheric pressure or reduced pressure, the shaped bodies being, after binder removal, transferred in their container without contact with air into a sintering furnace and being sintered therein according to the prior art.

REFERENCES:
patent: 3708285 (1978-01-01), Scheyer et al.
patent: 4778515 (1988-10-01), Kemp, Jr. et al.
patent: 4917859 (1990-04-01), Hamo
patent: 5439964 (1995-08-01), Ohst et al.
Randell M. German "Powder Metallurgy Science" Metal Powder Industries Federation (1984) Princeton, New Jersey pp. 189-194.

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