Singlet oxygen oxidation of organic substrates

Details Singlet oxygen oxidation of organic substrates Singlet oxygen oxidation of organic substrates

2005-10-18

2005-10-18

Price, Elvis O. (Department: 1621)

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

C568S469900, C568S558000, C568S567000, C568S568000, C568S577000

Reexamination Certificate

active

06956137

ABSTRACT:
The invention relates to a method for oxidizing organic substrates using1O2in which hydrophobic organic substrates that react with1O2 are added to an organic solvent in the presence of a heterogeneous or homogeneous catalyst with 30–70% being compr Afterwards, H2O2is catalytically decomposed into water and1O2, and the oxidation into corresponding oxidation products ensues.

REFERENCES:
Aubry, J. Am. chem. Soc., 1985, vol. 107, pp. 5844-5849.
Barton et al., J. Chem. Soc. Perkin Transactions 1, 1975, pp. 610-1614.
Barton et al., J. Chem. Soc., Perkin Transactions 1, 1975, pp. 1610-1614.
Van Laar et al., Chem. Commun., 1998, pp. 267-268.
Barton, Journal of the Chemical Society, Perkin Transactions 1, pp. 1610-1614 (1975).
Van Laar, Journal of the Chemical Society, Chemical Communications, pp. 267-268 (1998).
Aubry, Journal of the American Chemical Society, vol. 119, No. 23, pp. 5286-5294 (1997).
Aubry, Journal of Organic Chemistry, vol. 54, No. 3, pp. 726-728 (1989).

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