Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component
Patent
1995-03-16
1997-08-19
Langel, Wayne
Chemistry of inorganic compounds
Modifying or removing component of normally gaseous mixture
Sulfur or sulfur containing component
42324301, 423235, 110345, C01B 1722
Patent
active
056585470
ABSTRACT:
The removal of SO.sub.x and particulates, and preferably also NO.sub.x, from the combustion gases of a large boiler, is simplified while efficiency is improved. In a primary treatment zone, a slurry comprising an alkaline SO.sub.x -reducing composition and preferably a nitrogen-containing composition effective to reduce NO.sub.x, is introduced into combustion gases at a temperature of from about 900.degree. to about 1300.degree. C. The gases are cooled by initial contact with steam-generating means, and then by contact with an gas-to-gas heat exchanger. Cooled gases are then subjected to a secondary treatment in which they are first humidified and further cooled by introduction of a water spray or aerosol to reduce the temperature to 100.degree. C. or below. Contact between the SO.sub.x -reducing composition and the humidified gases is maintained for a reaction period of at least 2 seconds. Particulate solids are then separated from the gases with a fabric filter. The cleaned gases are reheated by the gas-to-gas heat exchanger prior to discharge to the atmosphere. Reductions of SO.sub.x of greater than 80% are achieved, preferably 90 to 95%.
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Comparato Joseph R.
Hofmann John E.
Michalak Stanislaw
Harding Amy M.
Langel Wayne
Nalco Fuel Tech
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