Silylation method

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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548473, 549214, 556426, 556431, 556437, 556432, 556435, 556415, 556416, 556417, 556422, 556436, 556443, 556444, 556450, 556452, 556453, 556456, 556460, 556468, C07F 708, C07F 710, C07F 718

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active

049181971

ABSTRACT:
A method is provided for silylating aromatic acylhalide by effecting reaction between an aromatic acylhalide and halogenated polysilane in the presence of an effective amount of a supported transition metal catalyst, such as a transition metal catalyst supported by an organic or inorganic substrate.

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Grubbs, R. H., "Hybrid-Phase Catalysts", Chemtech, (Aug. 1977), pp. 512-518.
Allum, K. G. et al., "Supported Transition Metal Complexes, II, Silica as the Support", Journal of Organometallic Chemistry 87, (1975), pp. 203-216.
Capka, M. & Hetflejs, J., "Hydrosilylation Catalysed by Transition Metal Complexes Coordinately Bound to Inorganic Supports", Collection Czechoslov. Chem. Commun. 39, (1974), pp. 154-166.
Pittman et al., Journal of the American Chemical Society; "Catalytic Reactions Using Polymer-Bound vs. Homogeneous Complexes of Nickel, Rhodium and Ruthenium", (1975), pp. 1742-1748.
Bailey et al., Chemical Reviews, vol. 81, No. 2, (1981), "Immobilized Transition-Metal Carbonyls and Related Catalysts"; pp. 109-148.

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