Silyl carbamates and synthesis thereof

Details Silyl carbamates and synthesis thereof Silyl carbamates and synthesis thereof

1982-12-28

1985-01-29

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

C07F 710, C07F 718

Patent

active

044967543

ABSTRACT:
Silyl carbamates are produced by the reaction under suitable reaction conditions of silanes bearing at least one silicon-hydrogen bond of the formula: R.sub.4-x SiH.sub.x with an ammonium carbamate of the formula: R'R"NH.sub.2.sup..sym. R'R"NCO.sub.2.sup..crclbar.. This novel route is much simpler and more direct than those previously known and provides a new classes of silyl carbamates.

REFERENCES:
patent: 4400526 (1983-08-01), Kanner et al.
Lappert and Prokai, Adv. Organometal. Chem., 5 (1967) 225.
Cragg and Lappert, J. Chem. Soc., A (1966) 82.
Berkofer and Sommer, J. Organometal Chem. 35, (1972) C 15.
Berkofer and Sommer, J. Organometal. Chem., 99, (1975) C1.
Sheludyakov et al., Zh. Obshch Khim., 47, (1977) 1515.
Jung and Lyster, J. Chem. Soc., Chem. Comm. (1978) 315.
Sheludyak et al., Zh. Obshch, Khim., 45, (1975) 479.

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