Silyl, benzyl, p-nitrobenyl, or methyl esters of diazoacetate, a

Details Silyl, benzyl, p-nitrobenyl, or methyl esters of diazoacetate, a Silyl, benzyl, p-nitrobenyl, or methyl esters of diazoacetate, a

1984-01-23

1985-06-25

Higel, Floyd D.

Organic compounds -- part of the class 532-570 series

Organic compounds

Diazo or diazonium

534556, 534560, C07C11300

Patent

active

045255822

ABSTRACT:
A novel synthon useful in the conversion of penicillin is a compound of the formula ##STR1## wherein R.sub.3 is a number of the group consisting of trimethyl-silyl, t-butyl dimethyl silyl, trimethyl silyl, methyl, benzyl or nitrobenzyl, and R.sub.5 is the same or different member of the group R.sub.3 is prepared by the naphthalene sulfonyl azide exchange reaction with benzyl acetoacetate, p-nitrobenzylacetoacetate, or methylacetoacetate to obtain the corresponding 2-diazo compound which is then silylated in hexamethyl-disalazine.

REFERENCES:
patent: 4073799 (1978-02-01), Kondo et al.
Kaufmann et al., Index Chemicus, vol. 31 #102512 (1968).
Regitz, Ber. Deut. Chem. Gesell., vol. 99, pp. 3128-3147 (1966).

Affiliated with

Also associated with

Rating

Silyl, benzyl, p-nitrobenyl, or methyl esters of diazoacetate, a does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Silyl, benzyl, p-nitrobenyl, or methyl esters of diazoacetate, a, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Silyl, benzyl, p-nitrobenyl, or methyl esters of diazoacetate, a will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-555862